Support interaction of Ni nanocluster based catalysts applied in CO2 reforming

作者: Subhasis Das , Sharvani Thakur , Arijit Bag , Manveer Singh Gupta , Prasenjit Mondal

DOI: 10.1016/J.JCAT.2015.06.010

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摘要: Surface-tuned mesoporous alumina has been prepared using a template-assisted solvo thermal method, and Ni nanoclusters (4–5 nm) have been synthesized on this support using a very facile organic matrix decomposition approach to dry reforming of methane. The catalyst system demonstrates very good catalytic activity toward CH 4 and CO 2 conversion (> 90%), with a H 2/CO ratio in syngas of almost unity, remarkable stability for more than 100 h, and is proven to be a very interesting catalyst system in dry reforming with methane. Both …

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