Reactions of the clusters [Os3(CO)10(MeCN)2)] and [Ru3(CO)12] with (2-aminophenyl)phosphine P(2-NH2C6H4)H2. A comparison of the reactivity of amino and phosphino groups with clusters
作者： Alejandro J. Arce , Rubén Machado , Ysaura De Sanctis , Teresa González , Reinaldo Atencio
DOI: 10.1016/S0020-1693(02)01259-8
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摘要: Abstract The reaction of (2-aminophenyl)phosphine P(2-NH 2 C 6 H 4 )H with [Os 3 (CO) 10 (MeCN) ] gives the compounds 11 {P(2-NH }] ( 1 ), [1,2-Os } ) and (μ-H)(CO) {μ-P(2-NH )H}] ). Thermolysis in cyclohexane affords quantitative yields (μ-H) 9 {μ -P(2-NH )}] However, direct [Ru 12 only nonacarbonyl species 5 phosphino group coordinates more favorably than amino PH bond activation is favored over coordination.
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