Interpolymer radical coupling: A toolbox complementary to controlled radical polymerization

摘要: Abstract The current review focuses on the relevance and practical benefit of interpolymer radical coupling methods. latter are developing rapidly constitute a perfectly complementary macromolecular engineering toolbox to controlled polymerization techniques (CRP). Indeed, all structures formed by CRP likely be prone reactions, which multiply available synthetic possibilities. Basically, systems can divided in two main categories. first one, including atom transfer (ATRC), silane abstraction (SRAA) cobalt-mediated (CMRC), relies recombination macroradicals produced from dormant species. second nitroxide (ATNRC), single electron (SETNRC), enhanced spin capturing (ESCP) nitrone/nitroso mediated (NMRC), makes use scavenger order promote conjugation polymer chains. More than compilation achievements, present additionally aims emphasize particularities, potential limitations each system.