Template-Free Synthesis of Sb2S3 Hollow Microspheres as Anode Materials for Lithium-Ion and Sodium-Ion Batteries.
作者： Jianjun Xie , Li Liu , Jing Xia , Yue Zhang , Min Li
DOI: 10.1007/S40820-017-0165-1
关键词:
摘要: Hierarchical Sb2S3 hollow microspheres assembled by nanowires have been successfully synthesized a simple and practical hydrothermal reaction. The possible formation process of this architecture was investigated X-ray diffraction, focused-ion beam-scanning electron microscopy dual-beam system, transmission microscopy. When used as the anode material for lithium-ion batteries, manifest excellent rate property enhanced lithium-storage capability can deliver discharge capacity 674 mAh g−1 at current density 200 mA g−1 after 50 cycles. Even high 5000 mA g−1, 541 mAh g−1 is achieved. also display prominent sodium-storage maintain reversible 384 mAh g−1 remarkable lithium/sodium-storage may be attributed to synergetic effect its nanometer size three-dimensional hierarchical architecture, outstanding stability sufficient interior void space, which buffer volume expansion.
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Hongshuai Hou, Mingjun Jing, Zhaodong Huang, Yingchang Yang, Yan Zhang, Jun Chen, Zhibin Wu, Xiaobo Ji, One-Dimensional Rod-Like Sb2S3-Based Anode for High-Performance Sodium-Ion Batteries ACS Applied Materials & Interfaces. ,vol. 7, pp. 19362- 19369 ,(2015) , 10.1021/ACSAMI.5B05509
Zichao Zhang, Li Li, Qi Xu, Bingqiang Cao, 3D hierarchical Co3O4 microspheres with enhanced lithium-ion battery performance RSC Advances. ,vol. 5, pp. 61631- 61638 ,(2015) , 10.1039/C5RA11472A
Heng-guo Wang, Yinghui Wang, Yanhui Li, Yuchun Wan, Qian Duan, Exceptional electrochemical performance of nitrogen-doped porous carbon for lithium storage Carbon. ,vol. 82, pp. 116- 123 ,(2015) , 10.1016/J.CARBON.2014.10.041
Heng-guo Wang, Yuqi Zhou, Yu Shen, Yanhui Li, Qinghui Zuo, Qian Duan, Fabrication, formation mechanism and the application in lithium-ion battery of porous Fe2O3 nanotubes via single-spinneret electrospinning Electrochimica Acta. ,vol. 158, pp. 105- 112 ,(2015) , 10.1016/J.ELECTACTA.2015.01.149
Jinli Tan, Li Liu, Shengping Guo, Hai Hu, Zichao Yan, Qian Zhou, Zhifeng Huang, Hongbo Shu, Xiukang Yang, Xianyou Wang, The electrochemical performance and mechanism of cobalt (II) fluoride as anode material for lithium and sodium ion batteries Electrochimica Acta. ,vol. 168, pp. 225- 233 ,(2015) , 10.1016/J.ELECTACTA.2015.04.029
Xiao Ming Yin, Cheng Chao Li, Ming Zhang, Quan Yi Hao, Shuang Liu, Li Bao Chen, Tai Hong Wang, One-Step Synthesis of Hierarchical SnO2 Hollow Nanostructures via Self-Assembly for High Power Lithium Ion Batteries Journal of Physical Chemistry C. ,vol. 114, pp. 8084- 8088 ,(2010) , 10.1021/JP100224X
Zichao Yan, Li Liu, Jinli Tan, Qian Zhou, Zhifeng Huang, Dongdong Xia, Hongbo Shu, Xiukang Yang, Xianyou Wang, One-pot synthesis of bicrystalline titanium dioxide spheres with a core–shell structure as anode materials for lithium and sodium ion batteries Journal of Power Sources. ,vol. 269, pp. 37- 45 ,(2014) , 10.1016/J.JPOWSOUR.2014.06.150
John B. Goodenough, Kyu-Sung Park, The Li-ion rechargeable battery: a perspective. Journal of the American Chemical Society. ,vol. 135, pp. 1167- 1176 ,(2013) , 10.1021/JA3091438
Yaoyao Zhu, Ping Nie, Laifa Shen, Shengyang Dong, Qi Sheng, Hongsen Li, Haifeng Luo, Xiaogang Zhang, High rate capability and superior cycle stability of a flower-like Sb2S3 anode for high-capacity sodium ion batteries Nanoscale. ,vol. 7, pp. 3309- 3315 ,(2015) , 10.1039/C4NR05242K
Chunshuang Yan, Gang Chen, Dahong Chen, Jian Pei, Jingxue Sun, Haiming Xu, Yongqiang Zhang, Zhuangzhuang Qiu, Double surfactant-directed controllable synthesis of Sb2S3 crystals with comparable electrochemical performances CrystEngComm. ,vol. 16, pp. 7753- 7760 ,(2014) , 10.1039/C4CE00871E