Emission analysis of RE3+ (RE=Eu, Sm, Dy):MgY4Si3O13 phosphors

作者: B. Sudhakar Reddy , Monali R. Kadukar , Hyeong-Yong Hwang , Byoung Seung Ham , S. Sailaja

DOI: 10.1016/J.PHYSB.2015.01.029

关键词:

摘要: Abstract A series of Eu 3+ , Sm and Dy ion doped magnesium yttrium silicate [MgY 4 Si 3 O 13 ] phosphors was synthesized using the solid-state reaction method with a grain size approximately 500 nm in hexagonal symmetry. The photoluminescence (PL) spectra :MgY exhibit bright red, orange-red yellow emissions at 615 nm ( 5 D 0 → 7 F 2 ), 603 nm G 52 6 H 7/2 574 nm 9/2 13/2 respectively. thermoluminescence (TL) displays maximum intensity consistently 10 mol% concentrations, single glow peak around 165 °C (Eu -activated phosphor), 230 °C (Sm (Dy trap parameters such as order kinetics b activation energy E frequency factor S Balarin parameter γ ) associated most intensive these were finally determined by analyzing their line-shapes on basis Chen's method.

参考文章(32)
K. Vemasevana Raju, C. Nageswara Raju, P. Giridhar, B. Vengala Rao, B. Sudhakar Reddy, M. Bhushana Reddy, S. Sailaja, Synthesis and luminescence properties of Ca3Ga2Si3O12:RE3+ (RE = Eu/Tb) powder phosphors. Luminescence. ,vol. 26, pp. 680- 684 ,(2011) , 10.1002/BIO.1295
Young-Hyun Song, Min-Ji Lee, Ye-Lim Song, Gill Sang Han, Karuppanan Senthil, Mong-Kwon Jung, Hyun Suk Jung, Dae-Ho Yoon, Preparation and luminescence characteristics of single-phase rod-like BaSi2O2N2:Eu2+ phosphor with new synthetic route for white light generation Materials Letters. ,vol. 129, pp. 178- 181 ,(2014) , 10.1016/J.MATLET.2014.05.012
Li GUAN, Litao JIN, Shuqing GUO, Yunfeng LIU, Xu LI, Qinglin GUO, Zhiping YANG, Guangsheng FU, Luminescent properties of Eu3+-doped BaZrO3 phosphor for UV white light emitting diode Journal of Rare Earths. ,vol. 28, pp. 292- 294 ,(2010) , 10.1016/S1002-0721(10)60362-6
Wenyu Zhao, Shengli An, Bin Fan, Songbo Li, Photoluminescence properties of MgY4Si3O13:Gd3+, Tb3+ under vacuum ultraviolet excitation Optical Materials. ,vol. 35, pp. 1748- 1751 ,(2013) , 10.1016/J.OPTMAT.2013.05.031
Meng Jian-Xin, Yang Chuang-Tao, Chen Qing-Qing, Photoluminescence characterization of Ce3+ and Dy3+ doped Li2CaGeO4 phosphors Journal of Luminescence. ,vol. 130, pp. 1320- 1323 ,(2010) , 10.1016/J.JLUMIN.2010.02.047
Reuven Chen, On the Calculation of Activation Energies and Frequency Factors from Glow Curves Journal of Applied Physics. ,vol. 40, pp. 570- 585 ,(1969) , 10.1063/1.1657437
Chuqiao Zhu, Siguo Xiao, Jianwen Ding, Xiaoliang Yang, Renfeng Qiang, Synthesis and photoluminescent properties of Eu3+-doped (1−x)CaO–xLi2O–WO3 phosphors Materials Science and Engineering: B. ,vol. 150, pp. 95- 98 ,(2008) , 10.1016/J.MSEB.2008.03.015
Fan-Gui Meng, Xin-Min Zhang, Hyo Jin Seo, Optical properties of Sm3+ and Dy3+ ions in Gd2MoB2O9 host lattice Optics and Laser Technology. ,vol. 44, pp. 185- 189 ,(2012) , 10.1016/J.OPTLASTEC.2011.06.016
M.K. Chong, K. Pita, C.H. Kam, Photoluminescence of Y2O3:Eu3+ thin film phosphors by sol–gel deposition and rapid thermal annealing Journal of Physics and Chemistry of Solids. ,vol. 66, pp. 213- 217 ,(2005) , 10.1016/J.JPCS.2004.09.016
Xinmin Zhang, Hyo Jin Seo, Luminescence properties of novel Sm3+, Dy3+ doped LaMoBO6 phosphors Journal of Alloys and Compounds. ,vol. 509, pp. 2007- 2010 ,(2011) , 10.1016/J.JALLCOM.2010.10.119