Remarks concerning the theoretical explanation of Hund’s rule
作者： A. Lemberger , R. Pauncz
DOI: 10.1007/BF03156741
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摘要: According to the accepted theoretical explanation ofHund’s rule electronic interaction energy is smallest in ground state which of highest multiplicity. A breakdown total into one- and two-electron contributions case carbon atom based on self-consistent field calculations configuration treatment shows that this assumption not valid. our results main differences energies different terms arising from same are due one-electron energies.
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