On the effects of high temperature and high pressure on the hydrogen solubility in rhenium.
作者： Thomas Scheler , Olga Degtyareva , Eugene Gregoryanz
DOI: 10.1063/1.3652863
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摘要: In situ x-ray diffraction experiments on rhenium hydride compressed up to 46 GPa reveal a hydrogen solubility (x) significantly larger than the previously assumed saturation limit of x ~ 0.38(4). layered anti-CdI(2)-type structure hydride, was found increase 0.5 at 15 over time. When heated temperatures above 420 K pressures 23 GPa, undergoes an isomorphous phase transition into NiAs-type accompanied by in 0.85. The formation fully stoichiometric is discussed.
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sci-hub.se 参考文章(18)
Andreas Z�ttel, Hydrogen storage methods. Naturwissenschaften. ,vol. 91, pp. 157- 172 ,(2004) , 10.1007/S00114-004-0516-X
Olga Degtyareva, John E. Proctor, Christophe L. Guillaume, Eugene Gregoryanz, Michael Hanfland, Formation of transition metal hydrides at high pressures Solid State Communications. ,vol. 149, pp. 1583- 1586 ,(2009) , 10.1016/J.SSC.2009.07.022
Thomas Scheler, Olga Degtyareva, Miriam Marqués, Christophe L. Guillaume, John E. Proctor, Shaun Evans, Eugene Gregoryanz, Synthesis and properties of platinum hydride Physical Review B. ,vol. 83, pp. 214106- ,(2011) , 10.1103/PHYSREVB.83.214106
A. P. Hammersley, S. O. Svensson, M. Hanfland, A. N. Fitch, D. Hausermann, Two-dimensional detector software: From real detector to idealised image or two-theta scan High Pressure Research. ,vol. 14, pp. 235- 248 ,(1996) , 10.1080/08957959608201408
H. Kawamura, M. Harada, Y. Akahama, K. Takemura, Hydrogen ordering in rhenium hydride: anti-CdI2 type structure of ReH0.36 Solid State Communications. ,vol. 130, pp. 59- 62 ,(2004) , 10.1016/J.SSC.2004.01.021
V. E. Antonov, I. T. Belash, O. V. Zharikov, A. V. Palnichenko, A Study on Superconductivities of High-Pressure Phases in the Re-H, Ru-H, Rh-H, and Ni-H Systems Physica Status Solidi B-basic Solid State Physics. ,vol. 142, ,(1987) , 10.1002/PSSB.2221420246
K. Syassen, Ruby under pressure High Pressure Research. ,vol. 28, pp. 75- 126 ,(2008) , 10.1080/08957950802235640
Lyci George, Surendra K. Saxena, Structural stability of metal hydrides, alanates and borohydrides of alkali and alkali- earth elements: A review International Journal of Hydrogen Energy. ,vol. 35, pp. 5454- 5470 ,(2010) , 10.1016/J.IJHYDENE.2010.03.078
Michael Hanfland, John E. Proctor, Christophe L. Guillaume, Olga Degtyareva, Eugene Gregoryanz, High-pressure synthesis, amorphization, and decomposition of silane. Physical Review Letters. ,vol. 106, pp. 095503- ,(2011) , 10.1103/PHYSREVLETT.106.095503
T. Atou, J.V. Badding, In Situ Diffraction Study of the Formation of Rhenium Hydride at High Pressure Journal of Solid State Chemistry. ,vol. 118, pp. 299- 302 ,(1995) , 10.1006/JSSC.1995.1348