摘要: This article reviews current efforts towards quantitative prediction of rheological properties industrial polymer resins, based upon their polydisperse branched molecular structure. involves both an understanding how reactor and reaction conditions influence the distribution chain lengths branch placement (which is province engineering) structures in turn give rise to rheology (the physics). Both fields are reviewed at introductory level, focussing particular on developments theoretical for entangled model polymers polymers. Finally, we discuss three classes which engineering physics have been truly combined produce predictions from rheology. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Phys. 2015, 53, 123–141
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Percy A. Small, Long-chain branching in polymers Macroconformation of Polymers. pp. 1- 64 ,(1975) , 10.1007/3-540-07252-7_1
Paul J. Flory, Principles of polymer chemistry ,(1953)
Masao Doi, Sam F Edwards, The theory of polymer dynamics Oxford University Press. ,(1986)
Xue Chen, Chunxia Costeux, Ronald G. Larson, Characterization and prediction of long-chain branching in commercial polyethylenes by a combination of rheology and modeling methods Journal of Rheology. ,vol. 54, pp. 1185- 1205 ,(2010) , 10.1122/1.3479044
T. C. B. McLeish, Why, and when, does dynamic tube dilation work for stars? Journal of Rheology. ,vol. 47, pp. 177- 198 ,(2003) , 10.1122/1.1529174
M. Kapnistos, D. Vlassopoulos, J. Roovers, L. G. Leal, Linear Rheology of Architecturally Complex Macromolecules: Comb Polymers with Linear Backbones Macromolecules. ,vol. 38, pp. 7852- 7862 ,(2005) , 10.1021/MA050644X
Zuowei Wang, Xue Chen, Ronald G. Larson, Comparing tube models for predicting the linear rheology of branched polymer melts Journal of Rheology. ,vol. 54, pp. 223- 260 ,(2010) , 10.1122/1.3301246
T. Samurkas, J. M. Dealy, R. G. Larson, Strong Extensional and Shearing Flows of a Branched Polyethylene Journal of Rheology. ,vol. 33, pp. 559- 578 ,(1989) , 10.1122/1.550028
E. van Ruymbeke, J. J. M. Slot, M. Kapnistos, P. A. M. Steeman, Structure and rheology of branched polyamide 6 polymers from their reaction recipe Soft Matter. ,vol. 9, pp. 6921- 6935 ,(2013) , 10.1039/C3SM50226K
R. G. Larson, T. Sridhar, L. G. Leal, G. H. McKinley, A. E. Likhtman, T. C. B. McLeish, Definitions of entanglement spacing and time constants in the tube model Journal of Rheology. ,vol. 47, pp. 809- 818 ,(2003) , 10.1122/1.1567750