Manufacture of ketone derivatives of polyoxypropylene glycols

作者: Edward Thomas Marquis , John Ronald Sanderson

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摘要: MANUFACTURE OF KETONE DERIVATIVES POLYOXYPROPYLENE GLYCOLS (Docket No. 80,902-F) ABSTRACT DISCLOSURE Polyoxypropylene diketones are prepared by initially adding predetermined amounts of glacial acetic acid, a poly-oxypropylene glycol and, optionally, water, to reaction zone and thereafter an aqueous solution alkali metal or alkaline earth hypochlorite oxidant the with agitation under conditions including temperature about 10° 50°C., pressure 0 1,000 psig. total time 0.5 20 hours, whereby said polyoxypropylene will be substantially selectively converted corresponding diketone, recovering diketone.

参考文章(2)
Matsumoto Masakazu, Shiraishi Makoto, Polyvinyl alcohol product and process ,(1959)
Claude Gremmelmaier, Process for producing alkoxy ketones ,(1977)