Metal-Free, Radical Addition to AlkenesviaDesulfitative Chlorine Atom Transfer
作者： Lidong Cao , Karin Weidner , Philippe Renaud
关键词:
摘要: An efficient method for radical additions to unactivated alkenes via desulfitative chlorine-atom transfer is described. The reaction based on the use of readily available sulfonyl chlorides as starting materials and cheap initiators such azobisisobutyronitrile (AIBN), di-tert-butyldiazene (DTBD), dilauroyl peroxide (DLP). No transition metal catalyst required takes place under mild conditions at temperatures ≤85 °C.
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