Products of the gas-phase reactions of cis-3-hexen-1-ol with OH radicals and O3
作者： Sara M. Aschmann , Yonghui Shu , Janet Arey , Roger Atkinson
DOI: 10.1016/S1352-2310(97)00205-7
关键词:
摘要: Abstract Products of the gas-phase reactions OH radicals (in presence NO) and O3 with biogenic emission cis-3-hexen-1-ol have been investigated using gas chromatography flame ionization detection (GC-FID), combined chromatography-mass spectrometry (GC-MS), Fourier transform infrared spectroscopy (GC-FTIR), direct air sampling, atmospheric pressure tandem mass (API-MS). Propanal 3-hydroxypropanal were identified quantified from radical reactions, respective formation yields 0.746 ± 0.067 0.48−0.24+0.48 reaction 0.493 0.075 0.33−0.16+0.33 reaction. In addition, a hydroxynitrate molecular weight 179 [CH3CH2CH(OH)CH(ONO2)CH2CH2OH and/or CH3CH2CH(ONO2)CH(OH)CH2CH2OH] hydroxycarbonyl 132, expected to be CH3CH2CH(OH)CH(OH)CH2CHO, observed by API-MS analyses. The mechanisms are discussed.
harvard.edu
elsevier.com
sci-hub.se 参考文章(23)
Roger Atkinson, Gas-Phase Tropospheric Chemistry of Organic Compounds ,(1994)
Thomas D. Sharkey, Emission of low molecular mass hydrocarbons from plants Trends in Plant Science. ,vol. 1, pp. 78- 82 ,(1996) , 10.1016/S1360-1385(96)80038-0
Roger Atkinson, Sara M. Aschmann, Hydroxyl radical production from the gas-phase reactions of ozone with a series of alkenes under atmospheric conditions Environmental Science & Technology. ,vol. 27, pp. 1357- 1363 ,(1993) , 10.1021/ES00044A010
Roger Atkinson, Janet Arey, Sara M. Aschmann, Stephanie B. Corchnoy, Yonghui Shu, Rate constants for the gas‐phase reactions of cis‐3‐Hexen‐1‐ol, cis‐3‐Hexenylacetate, trans‐2‐Hexenal, and Linalool with OH and NO3 radicals and O3 at 296 ± 2 K, and OH radical formation yields from the O3 reactions International Journal of Chemical Kinetics. ,vol. 27, pp. 941- 955 ,(1995) , 10.1002/KIN.550271002
Roger Atkinson, Atmospheric reactions of alkoxy and ?-hydroxyalkoxy radicals International Journal of Chemical Kinetics. ,vol. 29, pp. 99- 111 ,(1997) , 10.1002/(SICI)1097-4601(1997)29:2<99::AID-KIN3>3.0.CO;2-F
W. Lwande, M. D. Bentley, Volatiles of Sorghum bicolor seedlings Journal of Natural Products. ,vol. 50, pp. 950- 952 ,(1987) , 10.1021/NP50053A034
Georg König, Monika Brunda, Hans Puxbaum, C Nicholas Hewitt, S Craig Duckham, Jochen Rudolph, Relative contribution of oxygenated hydrocarbons to the total biogenic VOC emissions of selected mid-European agricultural and natural plant species Atmospheric Environment. ,vol. 29, pp. 861- 874 ,(1995) , 10.1016/1352-2310(95)00026-U
Roger Atkinson, William P. L. Carter, Arthur M. Winer, James N. Pitts, An Experimental Protocol for the Determination of OH Radical Rate Constants with Organics Using Methyl Nitrite Photolysis as an OH Radical Source Journal of the Air Pollution Control Association. ,vol. 31, pp. 1090- 1092 ,(1981) , 10.1080/00022470.1981.10465331
Keiichi Ohta, Emission of hexenol from higher plants Geochemical Journal. ,vol. 18, pp. 135- 141 ,(1984) , 10.2343/GEOCHEMJ.18.135
Eric S. C. Kwok, Roger. Atkinson, Janet. Arey, Observation of Hydroxycarbonyls from the OH Radical-Initiated Reaction of Isoprene. Environmental Science & Technology. ,vol. 29, pp. 2467- 2469 ,(1995) , 10.1021/ES00009A046