Bulk heterojunction solar cells with thick active layers and high fill factors enabled by a bithiophene-co-thiazolothiazole push-pull copolymer
作者： J. Peet , L. Wen , P. Byrne , S. Rodman , K. Forberich
DOI: 10.1063/1.3544940
关键词:
摘要: A push-pull copolymer is presented which can be used in bulk heterojunction (BHJ) solar cells with active layers greater than 200 nm and fill factors above 60%. The efficiencies of most BHJ are limited by the fact that they have between 60 110 nm. While this thickness regime enables peak quantum (EQE) 60%–70%, ability to fabricate thicker devices would increase average EQE values thus device efficiencies. Discovery materials maintain high performance at large thicknesses will enable higher hero commercial viability technology.
scitation.org
harvard.edu
aip.org 
researchgate.net 
sci-hub.se 参考文章(16)
Itaru Osaka, Rui Zhang, Junying Liu, Detlef-M. Smilgies, Tomasz Kowalewski, Richard D. McCullough, Highly Stable Semiconducting Polymers Based on Thiazolothiazole Chemistry of Materials. ,vol. 22, pp. 4191- 4196 ,(2010) , 10.1021/CM101052B
Liang Liao, Liming Dai, Adam Smith, Michael Durstock, Jianping Lu, Jianfu Ding, Ye Tao, Photovoltaic-Active Dithienosilole-Containing Polymers Macromolecules. ,vol. 40, pp. 9406- 9412 ,(2007) , 10.1021/MA071825X
Iain McCulloch, Martin Heeney, Clare Bailey, Kristijonas Genevicius, Iain MacDonald, Maxim Shkunov, David Sparrowe, Steve Tierney, Robert Wagner, Weimin Zhang, Michael L. Chabinyc, R. Joseph Kline, Michael D. McGehee, Michael F. Toney, Liquid-crystalline semiconducting polymers with high charge-carrier mobility. Nature Materials. ,vol. 5, pp. 328- 333 ,(2006) , 10.1038/NMAT1612
Fred Wudl, Naraso, Two Poly(2,5-thienythiazolothiazole)s: Observation of Spontaneous Ordering in Thin Films† Macromolecules. ,vol. 41, pp. 3169- 3174 ,(2008) , 10.1021/MA071857K
I. Osaka, G. Sauvé, R. Zhang, T. Kowalewski, R. D. McCullough, Novel Thiophene‐Thiazolothiazole Copolymers for Organic Field‐Effect Transistors Advanced Materials. ,vol. 19, pp. 4160- 4165 ,(2007) , 10.1002/ADMA.200701058
Jack E. Parmer, Alex C. Mayer, Brian E. Hardin, Shawn R. Scully, Michael D. McGehee, Martin Heeney, Iain McCulloch, Organic bulk heterojunction solar cells using poly(2,5-bis(3-tetradecyllthiophen-2-yl)thieno[3,2,-b]thiophene) Applied Physics Letters. ,vol. 92, pp. 113309- ,(2008) , 10.1063/1.2899996
Itaru Osaka, Rui Zhang, Geneviève Sauvé, Detlef-M. Smilgies, Tomasz Kowalewski, Richard D. McCullough, High-Lamellar Ordering and Amorphous-Like π-Network in Short-Chain Thiazolothiazole−Thiophene Copolymers Lead to High Mobilities Journal of the American Chemical Society. ,vol. 131, pp. 2521- 2529 ,(2009) , 10.1021/JA801475H
Gang Lu, Hakan Usta, Chad Risko, Lian Wang, Antonio Facchetti, Mark A. Ratner, Tobin J. Marks, Synthesis, characterization, and transistor response of semiconducting silole polymers with substantial hole mobility and air stability. Experiment and theory. Journal of the American Chemical Society. ,vol. 130, pp. 7670- 7685 ,(2008) , 10.1021/JA800424M
In Hwan Jung, Jinyoung Yu, Eunjae Jeong, Jinseck Kim, Sooncheol Kwon, Hoyoul Kong, Kwanghee Lee, Han Young Woo, Hong-Ku Shim, Synthesis and Photovoltaic Properties of Cyclopentadithiophene‐Based Low‐Bandgap Copolymers That Contain Electron‐Withdrawing Thiazole Derivatives Chemistry: A European Journal. ,vol. 16, pp. 3743- 3752 ,(2010) , 10.1002/CHEM.200903064
M. C. Scharber, D. Mühlbacher, M. Koppe, P. Denk, C. Waldauf, A. J. Heeger, C. J. Brabec, Design Rules for Donors in Bulk‐Heterojunction Solar Cells—Towards 10 % Energy‐Conversion Efficiency Advanced Materials. ,vol. 20, pp. 579- 583 ,(2006) , 10.1002/ADMA.200501717