Molecular binding thermodynamics of spherical guests by β-cyclodextrins bearing aromatic substituents
作者： Nan Li , Yong Chen , Ying-Ming Zhang , Li-Hua Wang , Wen-Zhao Mao
DOI: 10.1016/J.TCA.2013.11.021
关键词:
摘要: The molecular binding behaviors of two β-cyclodextrin (β-CD) derivatives bearing 1, 2, 3-triazole moieties, ie mono-6-deoxy-6-{4-(8-oxymethylquinolino)[1, 2, 3] triazolyl}-β-CD (1) and mono-6-deoxy-6-{4-(8-oxymethylnaphthol)[1, 2, 3] triazolyl}-β-CD (3), and their analogs without 1, 2, 3-triazole moieties, ie mono-6-deoxy-6-(8-oxymethylquinolino)-β-CD (2) and mono-6-deoxy-6-(8-oxymethylnaphthol)-β-CD (4) toward spherical guests (±)-borneol and (±)-camphor were investigated to elucidate how substituent moiety of host affects the binding …
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