Recovery of americium(III) from low acid solutions using an emulsion liquid membrane containing PC-88A as the carrier extractant

作者: Surekha Chowta , P.K. Mohapatra , B.S. Tomar , K.M. Michael , A. Dakshinamoorthy

DOI: 10.5004/DWT.2009.959

关键词:

摘要: A liquid emulsion membrane (LEM) containing PC-88A (2-ethylhexylphosphonic acid-2-ethylhexyl monoester) as the carrier extractant and SPAN-80 surfactant was used to pre-concentrate Am3+ from dilute acid solutions. Out of various stripping agents evaluated internal phase, 0.1 M oxalic found be most effective. The effect factors such as: external phase pH, equilibration time, concentration, SPAN 80 volume ratio, etc. on mass transfer investigated. broken by addition solvents acetone actual obtained after breaking agreed well with that difference method.

参考文章(19)
A. Ramanujam, P. V. Achuthan, P. S. Dhami, R. Kannan, V. Gopalakrishnan, V. P. Kansra, R. H. Iyer, K. Balu, Separation of carrier-free 90Y from high level waste by supported liquid membrane using KSM-17 Journal of Radioanalytical and Nuclear Chemistry. ,vol. 247, pp. 185- 191 ,(2014) , 10.1023/A:1006756224011
R. K. Singh, P. M. Dhadke, Extraction of U(VI), Zr(IV) and Th(IV) from perchlorate media, by PC-88A Journal of Radioanalytical and Nuclear Chemistry. ,vol. 254, pp. 607- 612 ,(2002) , 10.1023/A:1021666827517
P. W. Naik, P. S. Dhami, S. K. Misra, U. Jambunathan, J. N. Mathur, Use of organophosphorus extractants impregnated on silica gel for the extraction chromatographic separation of minor actinides from high level waste solutions Journal of Radioanalytical and Nuclear Chemistry. ,vol. 257, pp. 327- 332 ,(2003) , 10.1023/A:1024783813193
S.P. Moulik, B.K. Paul, Structure, dynamics and transport properties of microemulsions Advances in Colloid and Interface Science. ,vol. 78, pp. 99- 195 ,(1998) , 10.1016/S0001-8686(98)00063-3
Kenneth L. Nash, A REVIEW OF THE BASIC CHEMISTRY AND RECENT DEVELOPMENTS IN TRIVALENT f-ELEMENTS SEPARATIONS Solvent Extraction and Ion Exchange. ,vol. 11, pp. 729- 768 ,(1993) , 10.1080/07366299308918184
Henry Kasaini, Fumiyuki Nakashio, Masahiro Goto, Application of emulsion liquid membranes to recover cobalt ions from a dual-component sulphate solution containing nickel ions Journal of Membrane Science. ,vol. 146, pp. 159- 168 ,(1998) , 10.1016/S0376-7388(98)00105-7