CC Hydrolases for Biocatalysis
作者： Elina Siirola , Annika Frank , Gideon Grogan , Wolfgang Kroutil
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摘要: Although CC bond hydrolases are distributed widely in Nature, they has as yet have received only limited attention the area of biocatalysis compared to their counterpart C-heteroatom hydrolases, such lipases and proteases. However, substrate range non-dependence on cofactors, suggest that these enzymes may considerable potential for applications synthesis. In addition, β-diketone hydrolase from Rhodococcus (OCH) known, catalyse formation interesting chiral intermediates. Further enzymes, kynureninase a meta-cleavage product (MhpC), able carbon-carbon formation, suggesting wider than previously envisaged. this review, distribution, catalytic characteristics described, with view assessing potentialfor use biocatalytic processes future.
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