Mass transfer and transport during purification of fructooligosaccharides by nanofiltration

作者: R.C. Kuhn , F. Maugeri Filho , V. Silva , L. Palacio , A. Hernández

DOI: 10.1016/J.MEMSCI.2010.09.031

关键词:

摘要: Abstract In this work, a process has been designed for the purification of fructooligosaccharides obtained by enzymatic transformation sucrose from sugar cane molasses. The protocol includes two nanofiltration stages with same membrane. first one is diafiltration process, at constant volume followed concentration. second stage consists in permeate to obtain concentrate similar its characteristics initial solution. allows getting purities over 90% yields around 80%. These processes are studied and modeled, taking into account effects resulting osmotic pressure changes resistance due solute adsorption on transport modeled assuming that there diffusion convection but hindered friction pore. steric partitioning, along an adequate mass balance differently sized molecules have also considered leading get pore size distribution

参考文章(31)
Weiyi Li, Jiding Li, Tianquan Chen, Cuixian Chen, Study on nanofiltration for purifying fructo-oligosaccharides: I. Operation modes Journal of Membrane Science. ,vol. 245, pp. 123- 129 ,(2004) , 10.1016/J.MEMSCI.2004.07.021
J. Jacob, P. Prádanos, J.I. Calvo, A. Hernández, G. Jonsson, Fouling kinetics and associated dynamics of structural modifications Colloids and Surfaces A: Physicochemical and Engineering Aspects. ,vol. 138, pp. 173- 183 ,(1998) , 10.1016/S0927-7757(97)00082-4
M.J. González-Muñoz, J.C. Parajó, Diafiltration of Eucalyptus wood autohydrolysis liquors: Mathematical modeling Journal of Membrane Science. ,vol. 346, pp. 98- 104 ,(2010) , 10.1016/J.MEMSCI.2009.09.023
Klaudia Wesolowska, Stanislaw Koter, Michal Bodzek, Modelling of nanofiltration in softening water Desalination. ,vol. 162, pp. 137- 151 ,(2004) , 10.1016/S0011-9164(04)00037-2
W LI, J LI, T CHEN, Z ZHAO, C CHEN, Study on nanofiltration for purifying fructo-oligosaccharides: II. Extended pore model Journal of Membrane Science. ,vol. 258, pp. 8- 15 ,(2005) , 10.1016/J.MEMSCI.2004.06.017
W.Richard Bowen, Julian S. Welfoot, Modelling the performance of membrane nanofiltration - critical assessment and model development Chemical Engineering Science. ,vol. 57, pp. 1121- 1137 ,(2002) , 10.1016/S0009-2509(01)00413-4
Y. L. Cheng, T. Y. Lee, Separation of fructose and glucose mixture by zeolite Y. Biotechnology and Bioengineering. ,vol. 40, pp. 498- 504 ,(1992) , 10.1002/BIT.260400408
J.A. Otero, O. Mazarrasa, J. Villasante, V. Silva, P. Prádanos, J.I. Calvo, A. Hernández, Three independent ways to obtain information on pore size distributions of nanofiltration membranes Journal of Membrane Science. ,vol. 309, pp. 17- 27 ,(2008) , 10.1016/J.MEMSCI.2007.09.065
V. Silva, P. Prádanos, L. Palacio, A. Hernández, Alternative pore hindrance factors: What one should be used for nanofiltration modelization? Desalination. ,vol. 245, pp. 606- 613 ,(2009) , 10.1016/J.DESAL.2009.02.026