Measurement of the absorption cross sections of unstable CS based on the dynamic equilibrium of CS2 and CS in the photolysis of CS2
作者： Yungang Zhang , Yongda Wang , Yunjie Liu , Xinyu Ai , Zhiguo Zhang
DOI: 10.1016/J.JQSRT.2020.106836
关键词:
摘要: Abstract The absorption cross sections, as important spectroscopic data, can be used for the identification and quantitative measurement of components. However, in view that carbon monosulfide (CS) is unstable highly reactive, it difficult to measure sections CS. Therefore, a method measuring CS based on dynamic equilibrium between disulfide (CS2) photolysis CS2 proposed paper, are obtained first time. Firstly, evaluating concentrations introduced, calculation formula given. Secondly, converted by increasing intensity incident light. Factors affecting conversion efficiency, such flow rate light, studied. Next, according relationship CS, concentration has been change concentration. Finally, (0.29 ± 0.01) × 10−16 cm2/molecule (2.15 ± 0.04) × 10−16 cm2/molecule provided at wavelengths 250.88 nm 257.60 nm, respectively.
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