New relationships between the characteristic energy of adsorption and the average effective diameter of carbon slit-like micropores: Part II. Adsorption of nitrogen and benzene in carbon slits and cylinders

摘要: Abstract The influence of the shape micropores on relationship between parameters Dubinin–Astakhov (DA) adsorption isotherm equation and average diameter pores (xav) is investigated. Nitrogen benzene are chosen to be adsorbates. For both molecules Horvath–Kawazoe (HK) type relationships for in cylindrical carbon derived. Line area potential models applied; moreover, benzene, random flat arrangement assumed. Basing model calculations, it shown that same equations relating DA as proposed recently slit-like valid also system only difference values constants occurring relations.