Recherches dans la série des cyclitols XLII. Synthèses de cyclitols tout‐cis dérivés du cyclopentane; préparation des cyclopentane‐tétrol et ‐ pentol tout‐cis
作者： F. G. Cocu , Th. Posternak
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摘要: All-cis cyclitols derived from cyclopentane have been prepared in two ways: (i) by LiAlH4 reduction of all-cis epoxypolyos; (ii) dimethyl sulfoxide treatment, the presence sodium hydrogencarbonate, brominated derivatives containing a neighbouring benzoyloxy group; under these conditions, halogen is replaced cis-oriented hydroxyl group. Thus cyclopentane-tetrol and -pentol prepared; their configuration has confirmed NMR. spectroscopy.
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