Water-stable lithium ion conducting solid electrolyte of iron and aluminum doped NASICON-type LiTi2(PO4)3

作者: P. Zhang , M. Matsui , Y. Takeda , O. Yamamoto , N. Imanishi

DOI: 10.1016/J.SSI.2014.04.017

关键词:

摘要: Abstract High lithium ion conductivity solid electrolytes of Li 1.4 Fe x Al 0.4 - x Ti1.6(PO 4 ) 3 (x = 0−0.4) with the NASICON-type structure were synthesized by using a sol−gel precursor. The highest electrical was obtained for 0.25 0.15 Ti 1.6 (PO sintered at 1040 °C 7 h in air. total, grain boundary, and bulk conductivities pellet 1.01 × 10 -3 , 2.17 × 10 1.81 × 10  S cm -1 25 °C, respectively. contribution electron (or hole) to total negligibly small. unstable water, but stable saturated LiOH LiCl aqueous solutions.

参考文章(26)
N. Ohta, K. Takada, L. Zhang, R. Ma, M. Osada, T. Sasaki, Enhancement of the High‐Rate Capability of Solid‐State Lithium Batteries by Nanoscale Interfacial Modification Advanced Materials. ,vol. 18, pp. 2226- 2229 ,(2006) , 10.1002/ADMA.200502604
Nobuyuki Imanishi, Satoshi Hasegawa, Tao Zhang, Atushi Hirano, Yasuo Takeda, Osamu Yamamoto, Lithium anode for lithium-air secondary batteries Journal of Power Sources. ,vol. 185, pp. 1392- 1397 ,(2008) , 10.1016/J.JPOWSOUR.2008.07.080
Tao Zhang, Nobuyuki Imanishi, Yuta Shimonishi, Atsushi Hirano, Jian Xie, Yasuo Takeda, Osamu Yamamoto, Nigel Sammes, Stability of a Water-Stable Lithium Metal Anode for a Lithium–Air Battery with Acetic Acid–Water Solutions Journal of The Electrochemical Society. ,vol. 157, ,(2010) , 10.1149/1.3271103
J KILNER, R BROOK, A study of oxygen ion conductivity in doped non-stoichiometric oxides Solid State Ionics. ,vol. 6, pp. 237- 252 ,(1982) , 10.1016/0167-2738(82)90045-5
Joykumar S. Thokchom, Binod Kumar, Composite effect in superionically conducting lithium aluminium germanium phosphate based glass-ceramic Journal of Power Sources. ,vol. 185, pp. 480- 485 ,(2008) , 10.1016/J.JPOWSOUR.2008.07.009
Hiromichi Aono, Eisuke Sugimoto, Yoshihiko Sadaoka, Nobuhito Imanaka, Gin‐ya Adachi, Ionic Conductivity of Solid Electrolytes Based on Lithium Titanium Phosphate Journal of The Electrochemical Society. ,vol. 137, pp. 1023- 1027 ,(1990) , 10.1149/1.2086597
Odile Bohnke, Quoc Nghi Pham, Anthony Boulant, Joel Emery, Tomas Šalkus, Maud Barré, H+/Li+ exchange property of Li3XLa2/3−XTiO3 in water and in humid atmosphere Solid State Ionics. ,vol. 188, pp. 144- 147 ,(2011) , 10.1016/J.SSI.2010.09.058
Yuta Shimonishi, Tao Zhang, Nobuyuki Imanishi, Dongmin Im, Dong Joon Lee, Atsushi Hirano, Yasuo Takeda, Osamu Yamamoto, Nigel Sammes, A study on lithium/air secondary batteries—Stability of the NASICON-type lithium ion conducting solid electrolyte in alkaline aqueous solutions Journal of Power Sources. ,vol. 196, pp. 5128- 5132 ,(2011) , 10.1016/J.JPOWSOUR.2011.02.023
Peng Zhang, Masaki Matsui, Atsushi Hirano, Yasuo Takeda, Osamu Yamamoto, Nobuyuki Imanishi, Water-stable lithium ion conducting solid electrolyte of the Li1.4Al0.4Ti1.6 − xGex(PO4)3 system (x = 0–1.0) with NASICON-type structure Solid State Ionics. ,vol. 253, pp. 175- 180 ,(2013) , 10.1016/J.SSI.2013.09.022