Hybridation et réactivité I.‐Introduction à une série d'articles‐Hydrolyse alcaline de l'acrylate et du propiolate de méthyle
作者： P. J. C. Fierens , J. Jaminet , P. Kruys
关键词:
摘要: The kinetic study of the alcaline hydrolysis methyl acrylate and propiolate, in acetone 70% — water 30%, have been made. rate propiolate is to fast be measured: at‐12° reaction finished less than 4 minutes. In case Arrhenius parameters are: E=12,9 Kcal./mole log PZ=8,27. Copyright © 1955 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim
ulb.ac.be
sci-hub.se 参考文章(13)
A. D. Walsh, 94. Factors influencing the strengths of bonds Journal of the Chemical Society (Resumed). pp. 398- 406 ,(1948) , 10.1039/JR9480000398
Mme L. Wilputte-Steinert, P. J. C. Fierens, H. Hannaert, Quelques remarques relatives aux équations linéaires de Hammett et de Winstein et Grunwald Bulletin des Sociétés Chimiques Belges. ,vol. 64, pp. 628- 634 ,(2010) , 10.1002/BSCB.19550640911
Mme. Alberte Pullman, Bernard Pullman, Natural hypsochromic shifts Discussions of The Faraday Society. ,vol. 9, pp. 46- 52 ,(1950) , 10.1039/DF9500900046
A. D. Walsh, Far ultra-violet spectra, ionisation potentials, and their significance in chemistry Quarterly Reviews, Chemical Society. ,vol. 2, pp. 73- 91 ,(1948) , 10.1039/QR9480200073
P. J. G. Fierens, J. Jaminet, P. Kruys, Hybridation et réactivité IV.‐Discussion générale Bulletin des Sociétés Chimiques Belges. ,vol. 64, pp. 557- 570 ,(2010) , 10.1002/BSCB.19550640906
C. A. Vernon, Kinetics and mechanisms of nucleophilic displacements in allylic systems. Part VIII. The reactivities of allylic chlorides towards bimolecular substitution without rearrangement Journal of the Chemical Society (Resumed). pp. 4462- 4470 ,(1954) , 10.1039/JR9540004462
C. A. Vernon, The kinetics and mechanisms of nucleophilic displacements in allylic systems. Part V. Reactivities of allylic halides by the S N1 mechanism of hydrolysis Journal of the Chemical Society (Resumed). pp. 423- 428 ,(1954) , 10.1039/JR9540000423
A. D. Walsh, The properties of bonds involving carbon Discussions of The Faraday Society. ,vol. 2, pp. 18- 25 ,(1947) , 10.1039/DF9470200018
Herbert C. Brown, Rosyln Silber. Fletcher, Chemical Effects of Steric Strains. I. The Effect of Structure upon the Hydrolysis of Tertiary Aliphatic Chlorides Journal of the American Chemical Society. ,vol. 71, pp. 1845- 1854 ,(1949) , 10.1021/JA01173A093
Lewis F. Hatch, Vincent Chiola, The Preparation and Properties of 3-Chloro-1-propyne and 1-Chloro-2-butyne Journal of the American Chemical Society. ,vol. 73, pp. 360- 362 ,(1951) , 10.1021/JA01145A121