Identification and quantification of (alkyl)benzenes in hydrocracked products of light cycle oil by GC-AED

作者: Taegon Kim , Khalid Alhooshani , Syed Ahmed Ali , Joo-Il Park , Mohammed Al-Yami

DOI: 10.1016/J.FUEL.2013.04.018

关键词:

摘要: Abstract GC–AED analysis was applied for detailed identification and quantification of (alkyl)benzenes in the hydrocracked light cycle oil (LCO) over alumina coated USY zeolite (ACZ) supported NiMoS catalyst. The specified AED peaks C H separated hydrocarbon species provide their H/C ratios. Several standard chemicals such as linear paraffins, (alkyl)cycloalkanes, (alkyl)benzenes, (alkyl)naphthalenes, 3-ring compounds were examined to calibrate area relative carbon hydrogen chromatogram atomic According combination ratio number, series from products LCO detected chromatograms successfully identified quantified. methodology application developed this study can be identify product light, middle, well heavy oils.

参考文章(16)
Joo-Il Park, Syed Ahmed Ali, Khalid Alhooshani, Nor Azizi, Jin Miyawaki, Taegon Kim, Youngjin Lee, Hyun-Seok Kim, Seong-Ho Yoon, Isao Mochida, Mild hydrocracking of 1-methyl naphthalene (1-MN) over alumina modified zeolite Journal of Industrial and Engineering Chemistry. ,vol. 19, pp. 627- 632 ,(2013) , 10.1016/J.JIEC.2012.09.014
Donald F. Gurka, Steven Pyle, Richard Titus, Environmental Applications of Gas Chromatography/Atomic Emission Detection Analytical Chemistry. ,vol. 69, pp. 2411- 2417 ,(1997) , 10.1021/AC9612739
Joo-Il Park, Jihn-Koo Lee, Jin Miyawaki, Young-Kwang Kim, Seong-Ho Yoon, Isao Mochida, Hydro-conversion of 1-methyl naphthalene into (alkyl)benzenes over alumina-coated USY zeolite-supported NiMoS catalysts Fuel. ,vol. 90, pp. 182- 189 ,(2011) , 10.1016/J.FUEL.2010.09.002
Pedro Castaño, Alazne Gutiérrez, Idoia Hita, José M Arandes, Andrés T Aguayo, Javier Bilbao, Deactivating Species Deposited on Pt–Pd Catalysts in the Hydrocracking of Light-Cycle Oil Energy & Fuels. ,vol. 26, pp. 1509- 1519 ,(2012) , 10.1021/EF2019676
Antonymuthu Stanislaus, Barry H. Cooper, Aromatic Hydrogenation Catalysis: A Review Catalysis Reviews-science and Engineering. ,vol. 36, pp. 75- 123 ,(1994) , 10.1080/01614949408013921
Alazne Gutiérrez, José M. Arandes, Pedro Castaño, Martín Olazar, Javier Bilbao, Preliminary studies on fuel production through LCO hydrocracking on noble-metal supported catalysts Fuel. ,vol. 94, pp. 504- 515 ,(2012) , 10.1016/J.FUEL.2011.10.010
Alazne Gutiérrez, José M. Arandes, Pedro Castaño, Andrés T. Aguayo, Javier Bilbao, Role of Acidity in the Deactivation and Steady Hydroconversion of Light Cycle Oil on Noble Metal Supported Catalysts Energy & Fuels. ,vol. 25, pp. 3389- 3399 ,(2011) , 10.1021/EF200523G
Michel Bouchy, Pierre Dufresne, Slavik Kasztelan, Hydrogenation and hydrocracking of a model light cycle oil feed. 1. Properties of a sulfided nickel-molybdenum hydrotreating catalyst Industrial & Engineering Chemistry Research. ,vol. 31, pp. 1592- 1602 ,(1992) , 10.1021/IE00012A006
Ki-Hyouk Choi, Yosuke Sano, Yozo Korai, Isao Mochida, An approach to the deep hydrodesulfurization of light cycle oil Applied Catalysis B-environmental. ,vol. 53, pp. 275- 283 ,(2004) , 10.1016/J.APCATB.2004.05.013