Spectral properties of Eu3+: B2O3-P2O5-R2SO4 glasses

作者: V. Aruna , N.Sooraj Hussain , K.Rajamohan Reddy , K. Annapurna , S. Buddhudu

DOI: 10.1016/S0167-577X(97)00093-1

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摘要: Abstract This paper reports the synthesis of three europium glasses in composition 44.5B 2 O 3 + 44.5P 5 10R SO 4 (where R = Li, Na and K). For these optical glasses, physical non-linearity property parameters have been computed from their densities refractive indices at different wavelengths (656.3, 589.3 486.1 nm), respectively. On excitation with 395 nm (Xe-Arc lamp radiation) Eu 3+ were found to be red fluorescent richness colour was high Li -glass compared K glass systems. The radiative properties transitions -glasses can understood by correlating measured photoluminescence spectra Judd-Ofelt intensity factors obtained recorded absorption spectra.

参考文章(14)
J. V. Sathyanarayana, K. Annapurna, T. Balaji, S. Buddhudu, Photoluminescence spectra of Sm3+ & Dy3+ doped fluoroborate glasses Ferroelectrics Letters Section. ,vol. 15, pp. 73- 88 ,(1993) , 10.1080/07315179308204242
S. Radhakrishna, A. Daud, Solid State Materials ,(1991)
J.V. Sathyanarayana, K. Annapurna, S. Buddhudu, Absorption and emission spectra of erbium3+ doped fluoroborate glasses Materials Research Bulletin. ,vol. 29, pp. 1263- 1270 ,(1994) , 10.1016/0025-5408(94)90150-3
R. Cases, M.A. Chamarro, R. Alcala, V.D. Rodriguez, Optical properties of Nd3+ and Dy3+ ions in ZnF22 based glasses Journal of Luminescence. pp. 509- 514 ,(1991) , 10.1016/0022-2313(91)90181-T
M. Hanumanthu, K. Annapurna, S. Buddhudu, Fluorescence characteristics of Nd3+ -doped heavy metal fluoride glasses Solid State Communications. ,vol. 80, pp. 315- 320 ,(1991) , 10.1016/0038-1098(91)90137-K
R. Reisfeld, E. Greenberg, R.N. Brown, M.G. Drexhage, C.K. Jørgensen, Fluorescence of europium(III) in a flouride glass containing zirconium Chemical Physics Letters. ,vol. 95, pp. 91- 94 ,(1983) , 10.1016/0009-2614(83)85072-6
R. Harinath, S. Buddhudu, F.J. Bryant, Luo Xi, Absorption and fluorescence properties of Eu3+ doped alkali mixed heavy metal fluoride glasses Solid State Communications. ,vol. 74, pp. 1147- 1152 ,(1990) , 10.1016/0038-1098(90)90728-T
G. Amaranath, S. Buddhudu, F.J. Bryant, Luo Xi, B. Yu, S. Huang, Luminescence properties of Nd3+ in mixed alkali flouride glasses Journal of Luminescence. ,vol. 50, pp. 17- 20 ,(1991) , 10.1016/0022-2313(91)90005-G
K.Subramanyam Naidu, S. Buddhudu, Absorption properties of Nd3+-doped (NaPO3)6-BaCl2-ZnCl2-RCl glasses Journal of Quantitative Spectroscopy and Radiative Transfer. ,vol. 47, pp. 515- 519 ,(1992) , 10.1016/0022-4073(92)90110-P
G Amaranath, S Buddhudu, F.J Bryant, Spectroscopic properties of Tb3+-doped fluoride glasses Journal of Non-crystalline Solids. ,vol. 122, pp. 66- 73 ,(1990) , 10.1016/0022-3093(90)90226-C