Kinetic modeling of the thermal decomposition of ammonia
作者： A.A. KONNOV , J. DE RUYCK
DOI: 10.1080/00102200008952125
关键词:
摘要: A detailed N/H reaction mechanism has been developed and validated in comparison with experimental data for ammonia pyrolysis in shock waves (Davidson et al., Int. J. Chem. Kinet, 1990, 22: 513). It has been shown that incorporation of the reactions with N2H3 and N2H4 into the mechanism significantly influences calculated rise-time and peak concentrations of the NH and NH2 radicals if the currently adopted rate constant of the reaction is employed. A sensitivity analysis reveals which reactions are critical for the quality …
sci-hub.se 参考文章(34)
Ronald K. Hanson, Siamak Salimian, Survey of Rate Constants in the N/H/O System Combustion Chemistry. pp. 361- 421 ,(1984) , 10.1007/978-1-4684-0186-8_6
P. Dransfeld, H. Gg. Wagner, Investigation of the Gas Phase Reaction N + NH2 → N2 + 2H at Room Temperature Zeitschrift für Physikalische Chemie. ,vol. 153, pp. 89- 97 ,(1987) , 10.1524/ZPCH.1987.153.PART_1_2.089
M. Röhrig, H.-J. Römming, H. Gg. Wagner, A direct measurement of the reaction NH3 + NH→2NH2 Berichte der Bunsengesellschaft für physikalische Chemie. ,vol. 98, pp. 1332- 1334 ,(1994) , 10.1002/BBPC.19940981020
J. V. Michael, J. W. Sutherland, R. B. Klemm, Rate constant for the reaction, atomic hydrogen + ammonia, over the temperature range, 750-1777 K The Journal of Physical Chemistry. ,vol. 90, pp. 497- 500 ,(1986) , 10.1021/J100275A029
Francis Westley, Table of recommended rate constraints for chemical reactions occurring in combustion National Bureau of Standards. ,(1979) , 10.6028/NBS.IR.79-1941
Taeho. Ko, Paul. Marshall, Arthur. Fontijn, Rate coefficients for the hydrogen atom + ammonia reaction over a wide temperature range The Journal of Physical Chemistry. ,vol. 94, pp. 1401- 1404 ,(1990) , 10.1021/J100367A037
John E. Dove, Wing S. Nip, A shock-tube study of ammonia pyrolysis Canadian Journal of Chemistry. ,vol. 57, pp. 689- 701 ,(1979) , 10.1139/V79-112
James A. Miller, Mitchell D. Smooke, Robert M. Green, Robert J. Kee, Kinetic Modeling of the Oxidation of Ammonia in Flames Combustion Science and Technology. ,vol. 34, pp. 149- 176 ,(1983) , 10.1080/00102208308923691
Anthony M. Dean, Mau-Song Chou, David Stern, Kinetics of rich ammonia flames International Journal of Chemical Kinetics. ,vol. 16, pp. 633- 653 ,(1984) , 10.1002/KIN.550160603
Mark T Allen, Richard A Yetter, Frederick L Dryer, Hydrogen/nitrous oxide kinetics—Implications of the NxHy species Combustion and Flame. ,vol. 112, pp. 302- 311 ,(1998) , 10.1016/S0010-2180(97)00128-4