Kinetics of the reaction of C2H5O2 with NO at 295 K

摘要: The reaction of C2H5O2 with NO in helium carrier gas at 295 K [He] = 1.6 × 1017 cm−3 has been studied using a flow reactor sampled by mass spectrometer. Because no parent molecular ion or suitable fragment produced could be detected, the was followed measuring formation NO2. In so doing, account had to taken small amount HO2 known present mixture, which also leads NO2 on NO. rate coefficient for total found (8.9 ± 3.0) 10−12 cm3/s, and path produces least 80% all C2H5O2.