Variable-Valent Rhenium Chemistry of Conjugated Nitrogenous Ligands: Structure and Reactivity
作者： Animesh Chakravorty
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摘要: The valence states of particular concern in this review are VI–I and the ligand types diimine, azoimine, imineamide azooximeall bidentate N,N-coordinating. Metal reduction potentials stability oxidation subject to control via variation nature extent N,N-chelation coligation. Back-bonding plays a major role determining isomer specificity, particularly domain III–I. Three mediated oxygen atom transfer processes have been scrutinized modeled: from ReVO tertiary phosphanes variable-spacer diphosphanes, water diimine oxime metal/coligand. Other reactivity topics include isomerizations associated with substitution, stable azo anion radical generation cleavage. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)
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