Synthesis of CuInS2 fluorescent nanocrystals and enhancement of fluorescence by controlling crystal defect

作者: Masato Uehara , Kosuke Watanabe , Yasuyuki Tajiri , Hiroyuki Nakamura , Hideaki Maeda

DOI: 10.1063/1.2987707

关键词:

摘要: For this study, Cu-In-S nanocrystals were developed as a low toxic fluorescent. The stoichiometric CuInS(2) synthesized facilely by heating solution of metal complexes and dodecanethiol. fluorescence would be originated from the crystal defect. We intentionally introduced defect in nanocrystal with prospect that intensity increased. structure products was analyzed using Raman spectroscopy other techniques. have many defects without phase separation observed bulk material. Consequently, quantum yield achieved approximately 5%. Moreover, increased up to 15% ZnS coating.

参考文章(38)
David L. Klein, Richard Roth, Andrew K. L. Lim, A. Paul Alivisatos, Paul L. McEuen, A single-electron transistor made from a cadmium selenide nanocrystal Nature. ,vol. 389, pp. 699- 701 ,(1997) , 10.1038/39535
Takayuki Negami, Naoki Kohara, Mikihiko Nishitani, Takahiro Wada, Preparation of Ordered Vacancy Chalcopyrite-Type $\bf CuIn_{3}Se_{5}$ Thin Films Japanese Journal of Applied Physics. ,vol. 33, pp. L1251- L1253 ,(1994) , 10.1143/JJAP.33.L1251
Thomas Hahn, Janko Cieslak, Heinrich Metzner, Jens Eberhardt, Udo Reislöhner, Mario Gossla, Wolfgang Witthuhn, Jürgen Kräußlich, Metastability of CuInS2 and its implications on thin-film growth Applied Physics Letters. ,vol. 88, pp. 171915- ,(2006) , 10.1063/1.2199472
B. Barcones, A. Pérez-Rodríguez, L. Calvo-Barrio, A. Romano-Rodríguez, J.R. Morante, E. Rudigier, I. Luck, J. Djordjevic, R. Scheer, In situ and ex situ characterisation of thermally induced crystallisation of CuInS2 thin films for solar cell Thin Solid Films. ,vol. 480, pp. 362- 366 ,(2005) , 10.1016/J.TSF.2004.11.093
Constantin Czekelius, Michael Hilgendorff, Lubomir Spanhel, Idriss Bedja, Martin Lerch, Gerd Müller, Ulrike Bloeck, Dang-Sheng Su, Michael Giersig, A Simple Colloidal Route to Nanocrystalline ZnO/CuInS2 Bilayers Advanced Materials. ,vol. 11, pp. 643- 646 ,(1999) , 10.1002/(SICI)1521-4095(199906)11:8<643::AID-ADMA643>3.0.CO;2-I
Kui Yu, Shanti Singh, Natasha Patrito, Virginia Chu, Effect of reaction media on the growth and photoluminescence of colloidal CdSe nanocrystals. Langmuir. ,vol. 20, pp. 11161- 11168 ,(2004) , 10.1021/LA049202P
YC Li, HZ Zhong, Rui Li, Yi Zhou, CH Yang, YF Li, None, High‐Yield Fabrication and Electrochemical Characterization of Tetrapodal CdSe, CdTe, and CdSexTe1–x Nanocrystals Advanced Functional Materials. ,vol. 16, pp. 1705- 1716 ,(2006) , 10.1002/ADFM.200500678
I. Oja, M. Nanu, A. Katerski, M. Krunks, A. Mere, J. Raudoja, A. Goossens, Crystal quality studies of CuInS2 films prepared by spray pyrolysis Thin Solid Films. ,vol. 480, pp. 82- 86 ,(2005) , 10.1016/J.TSF.2004.11.013
N. S. Orlova, I. V. Bodnar, E. A. Kudritskaya, Crystal Growth and Properties of the CuIn5S8 and AgIn5S8 Compounds Crystal Research and Technology. ,vol. 33, pp. 37- 42 ,(1998) , 10.1002/(SICI)1521-4079(1998)33:1<37::AID-CRAT37>3.0.CO;2-M
Tetsuya Yamamoto, Ilka V Luck, Roland Scheer, Hiroshi Katayama-Yoshida, Differences in the electronic structure and compensation mechanism between n-type Zn- and Cd-doped CuInS2 crystals Physica B-condensed Matter. ,vol. 273, pp. 927- 929 ,(1999) , 10.1016/S0921-4526(99)00556-6