Montmorillonite treated with Rhodamine-6G mechanochemically and in aqueous suspensions

作者: I. Lapides , S. Yariv , A. Landau , A. Zaban

DOI: 10.1023/A:1020649416016

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摘要: The mechanochemical solid-state adsorption of the cationic dye rhodamine-6G (R6G) by montmorillonite was investigated XRD and simultaneous DTA-TG. Five different mixtures R6G were investigated. They contained 10, 20, 35, 50 100 mmol per g clay. solid ground with clay for five minutes. Mixtures both in absence water (dry grinding) adding drops periodically, (wet grinding). There no differences between samples obtained wet or dry grinding. X-ray DTA data compared those R6G-montmorillonite from aqueous suspensions. products studies suggest that organic cations takes place on external surfaces whereas suspensions into interlayer space. In latter case final stages oxidation occur temperatures higher than neat former they at lower temperatures.

参考文章(21)
Fernando L�pez Arbeloa, Pilar Ruiz Ojeda, I�igo L�pez Arbeloa, Dimerization and trimerization of rhodamine 6G in aqueous solution. Effect on the fluorescence quantum yield Journal of the Chemical Society, Faraday Transactions. ,vol. 84, pp. 1903- 1912 ,(1988) , 10.1039/F29888401903
Shmuel Yariv, Gunter Kahr, Anton Rub, Thermal analysis of the adsorption of rhodamine 6G by smectite minerals Thermochimica Acta. ,vol. 135, pp. 299- 306 ,(1988) , 10.1016/0040-6031(88)87401-X
Shmuel Yariv, Ahmed Nasser, Ptahia Bar-on, Metachromasy in clay minerals. Spectroscopic study of the adsorption of crystal violet by laponite Journal of the Chemical Society, Faraday Transactions. ,vol. 86, pp. 1593- 1598 ,(1990) , 10.1039/FT9908601593
Sh. Yariv, Combined DTA-mass spectrometry of organo-clay complexes Journal of Thermal Analysis and Calorimetry. ,vol. 36, pp. 1953- 1961 ,(1990) , 10.1007/BF01914111
Fernando Lopez Arbeloa, I�aki Llona Gonzalez, Pilar Ruiz Ojeda, I�igo Lopez Arbeloa, Aggregate formation of rhodamine 6G in aqueous solution Journal of the Chemical Society, Faraday Transactions. ,vol. 78, pp. 989- 994 ,(1982) , 10.1039/F29827800989
M. J. Tapia Estevez, F. Lopez Arbeloa, T. Lopez Arbeloa, I. Lopez Arbeloa, Absorption and fluorescence properties of Rhodamine 6G adsorbed on aqueous suspensions of Wyoming montmorillonite Langmuir. ,vol. 9, pp. 3629- 3634 ,(1993) , 10.1021/LA00036A045
Shmuel Yariv, Max Müller-Vonmoos, Gunter Kahr, Anton Rub, Thermal analytic study of the adsorption of crystal violet by montmorillonite Thermochimica Acta. ,vol. 148, pp. 457- 466 ,(1989) , 10.1016/0040-6031(89)85247-5
S. Yariv, M. Müller Vonmoos, G. Kahr, A. Rub, Thermal analytic study of the adsorption of acridine orange by smectite minerals Journal of Thermal Analysis and Calorimetry. ,vol. 35, pp. 1997- 2008 ,(1989) , 10.1007/BF01911682
M. J. Tapia Estévez, F. López Arbeloa, T. López Arbeloa, I. López Arbeloa, R. A. Schoonheydt, Spectroscopic Study of the Adsorption of Rhodamine 6G on Laponite B for Low Loadings Clay Minerals. ,vol. 29, pp. 105- 113 ,(1994) , 10.1180/CLAYMIN.1994.029.1.12