The Synthesis, Self-Assembly and Self-Organisation of Polysilane Block Copolymers

摘要: Block copolymers containing polysilane blocks are unique in that the components possess electro-active properties and readily photodegradable. This review will discuss assess two major approaches to synthesis of block via pre-formed polymer chain coupling living polymerisation techniques. The self-organisation morphologies adopted thin films reviewed. Amphiphilic polysilane-containing self-assemble solvents selective for one a number examples highlighted. versatility these materials is highlighted by recent significant applications including preparation hollow cross-linked micellar aggregates aqueous solutions patterned film generation subsequently employed as templates growth cell cultures CaCO3.