Enantioselective discrimination of menthone enantiomers by using achiral liquid chromatography with circular dichroism detection and penicillamine-coated gold nanoparticles
作者： Mohamed Bouri , Rachid Salghi , Mohammed Zougagh , Angel Ríos
DOI: 10.1016/J.MICROC.2015.10.021
关键词:
摘要: Abstract A simple and rapid method is described for enantioselective discrimination of menthone enantiomers in peppermint oil samples. The includes a quick preparation procedure, followed by achiral liquid chromatography with circular dichroism detection (ALC-CD) an on-line penicillamine-coated gold nanoparticles (Pen-AuNPs) derivatization. involves the ALC-CD, as well enhancement their optical rotation signal was achieved presence Pen-AuNPs. Under optimal experimental conditions present maximum ellipticity between two optically active forms at wavelength 305 nm. calibration curve anisotropy factor (g) versus enantiomeric excess linear correlation coefficient (R2) 0.9984. precision evaluated UV (CD) signals suitable all cases (RSD
sci-hub.se 参考文章(36)
João Aires-de-Sousa, Johann Gasteiger, Prediction of enantiomeric selectivity in chromatography: Application of conformation-dependent and conformation-independent descriptors of molecular chirality Journal of Molecular Graphics & Modelling. ,vol. 20, pp. 373- 388 ,(2002) , 10.1016/S1093-3263(01)00136-X
Ernest Ludwig Eliel, Samuel H. Wilen, Lewis N. Mander, Stereochemistry of Organic Compounds ,(1962)
Daniel L Fedlheim, Colby A Foss, None, Metal Nanoparticles: Synthesis, Characterization, and Applications ,(2001)
James N. Miller, Jane C. Miller, Statistics and Chemometrics for Analytical Chemistry ,(2001)
T. Greber, Ž. Šljivančanin, R. Schillinger, J. Wider, B. Hammer, Chiral recognition of organic molecules by atomic kinks on surfaces. Physical Review Letters. ,vol. 96, pp. 056103- ,(2006) , 10.1103/PHYSREVLETT.96.056103
Cecilia Noguez, Ignacio L. Garzón, Optically active metal nanoparticles Chemical Society Reviews. ,vol. 38, pp. 757- 771 ,(2009) , 10.1039/B800404H
Nisha Shukla, Melissa A. Bartel, Andrew J. Gellman, Enantioselective Separation on Chiral Au Nanoparticles Journal of the American Chemical Society. ,vol. 132, pp. 8575- 8580 ,(2010) , 10.1021/JA908219H
Marco Bieri, Thomas Bürgi, Probing enantiospecific interactions between proline and an L-glutathione self-assembled monolayer by modulation excitation ATR-IR spectroscopy Journal of Physical Chemistry B. ,vol. 109, pp. 10243- 10250 ,(2005) , 10.1021/JP050197N
Robert M. Hazen, David S. Sholl, Chiral selection on inorganic crystalline surfaces. Nature Materials. ,vol. 2, pp. 367- 374 ,(2003) , 10.1038/NMAT879
Vincent Humblot, Sam Haq, Chris Muryn, Werner A. Hofer, Rasmita Raval, From local adsorption stresses to chiral surfaces: ( R , R )-tartaric acid on Ni(110) Journal of the American Chemical Society. ,vol. 124, pp. 503- 510 ,(2002) , 10.1021/JA012021E