Electronic transition dipole moment and radiative lifetime calculations of sodium dimer ion-pair states.
作者： Aydin Sanli , Bediha Beser , John R. Edwardson , Sylvie Magnier , Ergin H. Ahmed
DOI: 10.1063/1.4929925
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摘要: We report here ab initio calculated electronic transition dipole moments for the sodium dimer ion pair states of (1)Σg (+) symmetry. They vary strongly as a function internuclear distance because effect Na(+) + Na(-) potential, which also causes formation additional wells and shoulders in molecular potential energy curves. present computational study moment matrix elements lifetimes these ion-pair states.
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