Beiträge zur Chemie organometallischer metallacyclischer Nebengruppenmetallverbindungen: IV. Synthese von und seine Umsetzung mit Kohlenmonoxid zu Li2Ni6(CO)12(thf)6
作者： H.-O. Fröhlich , B. Hipler , B. Hofmann
DOI: 10.1016/0022-328X(92)86001-K
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摘要: Abstract LiCH 2 CH Li reacts with Ni(C 5 H ) in Et O to give ( 1 ). The Ni II complex is remarkably resistant β-elimination. DTA investigations showed that thermal decomposition takes place at 105°C. Interaction of carbon monoxide yields red-colored 6 (CO) 12 (thf) 4 IR studies the CO reaction very rapid even −78°C.
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