Uses of speciation techniques in biomonitoring for assessing human exposure to organic environmental chemicals

作者: Larry L Needham , Donald G Patterson , Dana B Barr , James Grainger , Antonia M Calafat

DOI: 10.1007/S00216-004-2975-5

关键词:

摘要: Speciation analysis has been used for many years to identify and measure different forms of a given chemical in environmental human samples. Although the term “speciation” is generally applied measurement inorganic chemicals, can also be measurements organic chemicals complex samples, such as media biological matrices. We present several examples achieving speciation by selecting appropriate matrix which specific chemical(s), analytical method, most accurate assessment exposure chemical. Much this information these techniques are transferable elements

参考文章(14)
Kayoko Kato, Manori J Silva, John A Reidy, Donald Hurtz 3rd, Nicole A Malek, Larry L Needham, Hiroyuki Nakazawa, Dana B Barr, Antonia M Calafat, None, Mono(2-ethyl-5-hydroxyhexyl) phthalate and mono-(2-ethyl-5-oxohexyl) phthalate as biomarkers for human exposure assessment to di-(2-ethylhexyl) phthalate. Environmental Health Perspectives. ,vol. 112, pp. 327- 330 ,(2004) , 10.1289/EHP.6663
Zsuzsanna Kuklenyik, John Ekong, Caroline D. Cutchins, Larry L. Needham, Antonia M. Calafat, Simultaneous measurement of urinary bisphenol A and alkylphenols by automated solid-phase extractive derivatization gas chromatography/mass spectrometry. Analytical Chemistry. ,vol. 75, pp. 6820- 6825 ,(2003) , 10.1021/AC0303158
Dana B Barr, Larry L Needham, None, Analytical methods for biological monitoring of exposure to pesticides: a review Journal of Chromatography B. ,vol. 778, pp. 5- 29 ,(2002) , 10.1016/S1570-0232(02)00035-1
Douglas M. Templeton, Freek Ariese, Rita Cornelis, Lars-Göran Danielsson, Herbert Muntau, Herman P. van Leeuwen, Ryszard Lobinski, Guidelines for terms related to chemical speciation and fractionation of elements. Definitions, structural aspects, and methodological approaches (IUPAC Recommendations 2000) Pure and Applied Chemistry. ,vol. 72, pp. 1453- 1470 ,(2000) , 10.1351/PAC200072081453
Zaiyou. Liu, Sarath R. Sirimanne, Donald G. Patterson, Larry L. Needham, John B. Phillips, Comprehensive two-dimensional gas chromatography for the fast separation and determination of pesticides extracted from human serum Analytical Chemistry. ,vol. 66, pp. 3086- 3092 ,(1994) , 10.1021/AC00091A016
D. G. Patterson, L. L. Needham, J. L. Pirkle, D. W. Roberts, J. Bagby, W. A. Garrett, J. S. Andrews, H. Falk, J. T. Bernert, E. J. Sampson, V. N. Houk, Correlation between serum and adipose tissue levels of 2,3,7,8-tetrachlorodibenzo-p-dioxin in 50 persons from Missouri. Archives of Environmental Contamination and Toxicology. ,vol. 17, pp. 139- 143 ,(1988) , 10.1007/BF01056017
Ronald L. Moolenaar, Brockton J. Hefflin, David L. Ashley, John P. Middaugh, Ruth A. Etzel, Methyl Tertiary Butyl Ether in Human Blood after Exposure to Oxygenated Fuel in Fairbanks, Alaska Archives of Environmental Health: An International Journal. ,vol. 49, pp. 402- 409 ,(1994) , 10.1080/00039896.1994.9954993
Donald G. Patterson, Larry. Hampton, Chester R. Lapeza, William T. Belser, Vaughn. Green, Louis. Alexander, Larry L. Needham, High-resolution gas chromatographic/high-resolution mass spectrometric analysis of human serum on a whole-weight and lipid basis for 2,3,7,8-tetrachlorodibenzo-p-dioxin. Analytical Chemistry. ,vol. 59, pp. 2000- 2005 ,(1987) , 10.1021/AC00142A023
L.L. Needham, V.W. Burse, S.L. Head, M.P. Korver, P.C. McClure, J.S. Andrews, D.L. Rowley, J. Sung, S.E. Kahn, Adipose tissue/serum partitioning of chlorinated hydrocarbon pesticides in humans Chemosphere. ,vol. 20, pp. 975- 980 ,(1990) , 10.1016/0045-6535(90)90208-B
Michael A. Bonin, David L. Ashley, Frederick L. Cardinali, Joan M. McCraw, Joe V. Wooten, Measurement of Methyl tert-Butyl Ether and tert-Butyl Alcohol in Human Blood by Purge-and-Trap Gas Chromatography-Mass Spectrometry Using an Isotope-Dilution Method Journal of Analytical Toxicology. ,vol. 19, pp. 187- 191 ,(1995) , 10.1093/JAT/19.3.187