Synthesis, characterization and magnetic properties of cobalt(II) and manganese(II) metal–organic frameworks assembled from 4,6-bis(imidazol-1-yl)isophthalic acid ligands
作者： Xiongwen Li , Jingzhi Yang , Ye Zhou , Bo Li , Liya Wang
DOI: 10.1007/S11243-018-0247-Z
关键词:
摘要: Two metal–organic frameworks of 4,6-bis(imidazol-1-yl)isophthalic acid (H2biip), general formula, {[M2(biip)2(H2O)]·EtOH2}n (M = Co (1), Mn (2)), have been synthesized under solvothermal conditions. Complexes 1 and 2 are isomorphic exhibit three-dimensional with a 2-nodal (4,8)-connected topological network, Point Symbol {416.612}{44.62}2. The magnetic properties the complexes were examined, indicating antiferromagnetic interactions between metal centers in temperature range from to 300 K.
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