Assembly and Phase Transitions within Colloidal Crystals

作者: Bo Li , Di Zhou , Yilong Han

DOI: 10.1038/NATREVMATS.2015.11

关键词:

摘要: Micrometre sized colloidal particles can be viewed as large atoms with tailorable size, shape and interactions. These building blocks assemble into extremely rich structures phases, in which the thermal motions of directly imaged tracked using optical microscopy. Hence, are excellent model systems for studying phase transitions, especially poorly understood kinetic nonequilibrium microscale processes. Advances colloid fabrication, assembly computer simulations have opened up numerous possibilities such research. In this Review, we describe recent progress study crystals composed tunable isotropic spheres, anisotropic active particles. We focus on advances crystallization, melting solid highlight challenges future perspectives transition studies within crystals.

参考文章(177)
P. G. Bolhuis, D. Frenkel, Siun-Choun Mau, David A. Huse, Entropy difference between crystal phases Nature. ,vol. 388, pp. 235- 236 ,(1997) , 10.1038/40779
William M. Jacobs, Aleks Reinhardt, Daan Frenkel, Rational design of self-assembly pathways for complex multicomponent structures. Proceedings of the National Academy of Sciences of the United States of America. ,vol. 112, pp. 6313- 6318 ,(2015) , 10.1073/PNAS.1502210112
J. Park, H. Elmlund, P. Ercius, J. M. Yuk, D. T. Limmer, Q. Chen, K. Kim, S. H. Han, D. A. Weitz, A. Zettl, A. P. Alivisatos, 3D structure of individual nanocrystals in solution by electron microscopy Science. ,vol. 349, pp. 290- 295 ,(2015) , 10.1126/SCIENCE.AAB1343
Anjan P. Gantapara, Weikai Qi, Marjolein Dijkstra, A novel chiral phase of achiral hard triangles and an entropy-driven demixing of enantiomers Soft Matter. ,vol. 11, pp. 8684- 8691 ,(2015) , 10.1039/C5SM01762A
Jérôme J. Crassous, Adriana M. Mihut, Linda K. Månsson, Peter Schurtenberger, Anisotropic responsive microgels with tuneable shape and interactions Nanoscale. ,vol. 7, pp. 15971- 15982 ,(2015) , 10.1039/C5NR03827H
M. H. J. Hagen, E. J. Meijer, G. C. A. M. Mooij, D. Frenkel, H. N. W. Lekkerkerker, Does C60 have a liquid phase Nature. ,vol. 365, pp. 425- 426 ,(1993) , 10.1038/365425A0
T. Kawasaki, H. Tanaka, Formation of a crystal nucleus from liquid Proceedings of the National Academy of Sciences of the United States of America. ,vol. 107, pp. 14036- 14041 ,(2010) , 10.1073/PNAS.1001040107