Synthesis and physico-chemical studies of neutral and chemically oxidized forms of bis(octaalkyloxyphthalocyaninato) lutetium

作者: Christian Piechocki , Jacques Simon , Jean-Jacques André , Daniel Guillon , Pierre Petit

DOI: 10.1016/0009-2614(85)85490-7

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摘要: Abstract The synthesis of three differently substituted bis(octaalkyloxyphthalocyaninato) lutetium complexes and their chemically oxidized hexachloroantimonate derivatives is described. Their thermotropic polymorphism studied using polarizing microscopy, differential scanning calorimetry, X-ray diffraction. A tentative model describing the columnar (discotic) structure one observed mesophases proposed. magnetic behavior neutral has been determined by ESR as a function temperature, showing presence spin per molecule. structural transitions are associated with change shape width signal.

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