COMBINATION OF BORANE-DIMETHYL SULFIDE COMPLEX WITH CATALYTIC SODIUM TETRAHYDROBORATE AS A SELECTIVE REDUCING AGENT FOR α-HYDROXY ESTERS. VERSATILE CHIRAL BUILDING BLOCK FROM (S)-(−)-MALIC ACID
作者： Seiki Saito , Takashi Hasegawa , Masami Inaba , Ryosuke Nishida , Toshikazu Fujii
DOI: 10.1246/CL.1984.1389
关键词:
摘要: Borane-dimethyl sulfide complex has proven to be an efficient and selective reducing agent in the presence of catalytic sodium tetrahydroborate for α-hydroxy esters as exemplified reduction dimethyl (S)-(−)-malate, providing versatile chiral building block four-carbon backbone.
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