A Comprehensive Study of Three Different Portable XRF Scanners to Assess the Soil Geochemistry of An Extensive Sample Dataset

作者: Ynse Declercq , Nele Delbecque , Johan De Grave , Philippe De Smedt , Peter Finke

DOI: 10.3390/RS11212490

关键词:

摘要: The assessment of soil elemental concentrations nowadays mainly occurs through conventional laboratory analyses. However, proximal sensing (PSS) techniques such as X-ray fluorescence (XRF) spectrometry are proving to reduce analysis time and costs, thus offer a worthy alternative Moreover, XRF scanners non-destructive can be directly employed in the field. Although use for is becoming widely accepted, most previous studies were limited one scanner, few samples, elements, or non-diverse sample database. Here, an extensive diverse database was used compare performance three different with results obtained Scanners benchtop mode built-in calibrations measure 15 elements. many samples Cu, S, P, Mg up 6, 12, 13, 5 times overestimated by XRF, empirical recalibration recommended, all produced acceptable results, even lighter Unexpectedly, did not seem depend on characteristics CaCO3 content. While performances will worse when expanding field, our show that easily applied non-experts reliably environments.

参考文章(31)
R. O. Bastos, F. L. Melquiades, G. E. V. Biasi, Correction for the effect of soil moisture on in situ XRF analysis using low-energy background X-Ray Spectrometry. ,vol. 41, pp. 304- 307 ,(2012) , 10.1002/XRS.2397
Arnaud Robin Schneider, Benjamin Cancès, Clément Breton, Marie Ponthieu, Xavier Morvan, Alexandra Conreux, Béatrice Marin, Comparison of field portable XRF and aqua regia/ICPAES soil analysis and evaluation of soil moisture influence on FPXRF results Journal of Soils and Sediments. ,vol. 16, pp. 438- 448 ,(2016) , 10.1007/S11368-015-1252-X
C. Vanhoof, K. A. Holschbach-Bussian, B. M. Bussian, R. Cleven, K. Furtmann, Applicability of portable XRF systems for screening waste loads on hazardous substances as incoming inspection at waste handling plants X-Ray Spectrometry. ,vol. 42, pp. 224- 231 ,(2013) , 10.1002/XRS.2485
Sangita Dhara, N.L. Misra, S.K. Aggarwal, Dieter Ingerle, Peter Wobrauschek, Christina Streli, Determinations of low atomic number elements in real uranium oxide samples using vacuum chamber total reflection X‐ray fluorescence X-Ray Spectrometry. ,vol. 43, pp. 108- 111 ,(2014) , 10.1002/XRS.2523
Aakriti Sharma, David C. Weindorf, DanDan Wang, Somsubhra Chakraborty, Characterizing soils via portable X-ray fluorescence spectrometer: 4. Cation exchange capacity (CEC) Geoderma. ,vol. 239, pp. 130- 134 ,(2015) , 10.1016/J.GEODERMA.2014.10.001
Erkki Mäkinen, Maarit Korhonen, Eeva-Liisa Viskari, Seija Haapamäki, Maaret Järvinen, Li Lu, Comparison of Xrf and Faas Methods in Analysing Cca Contaminated Soils Water Air and Soil Pollution. ,vol. 171, pp. 95- 110 ,(2006) , 10.1007/S11270-005-9017-6
Wenyou Hu, Biao Huang, David C. Weindorf, Yong Chen, Metals analysis of agricultural soils via portable X-ray fluorescence spectrometry. Bulletin of Environmental Contamination and Toxicology. ,vol. 92, pp. 420- 426 ,(2014) , 10.1007/S00128-014-1236-3
Tanja Radu, Dermot Diamond, Comparison of soil pollution concentrations determined using AAS and portable XRF techniques. Journal of Hazardous Materials. ,vol. 171, pp. 1168- 1171 ,(2009) , 10.1016/J.JHAZMAT.2009.06.062
Gianluca Bianchini, Claudio Natali, Dario Di Giuseppe, Luigi Beccaluva, Heavy metals in soils and sedimentary deposits of the Padanian Plain (Ferrara, Northern Italy): characterisation and biomonitoring Journal of Soils and Sediments. ,vol. 12, pp. 1145- 1153 ,(2012) , 10.1007/S11368-012-0538-5