Copolyesters and process for their production

作者: Stephen Hugh Collins , Leonard Frederick Wright , Paul Arthur Holmes

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摘要: High molecular weight copolymers containing 3-hydroxybutyrate residues, i.e. units of the formula and up to 50 mole % residues other hydroxy acids, viz where n is 0 or an integer and, if = 1 R 2 , 3 4 H, R' not methyl. The are made microbiologically: for part cultivation micro-organism under conditions such that polymer accumulated, e.g. by limitation a nutrient, nitrogen source, required growth but polyester accumulation. For at least this period accumulation substrate acid derivative thereof gives comonomer units. Propionic acid, which polymers 1, =R =H C H s preferred acid.

参考文章(2)
Stephen Hugh Collins, Leonard Frederick Wright, Paul Arthur Holmes, Beta-hydroxybutyrate polymers ,(1981)
Vernon F Coty, Microbial synthesis of polymers ,(1964)