Reversible transformation from amorphouse Na3Fe3(SO4)2(OH)6 to crystallized NaFe3(SO4)2(OH)6 Jarosite-type hydroxysulfate
作者： M. Gnanavel , O.I. Lebedev , P. Bazin , B. Raveau , V. Pralong
DOI: 10.1016/J.SSI.2015.05.013
关键词:
摘要: An amorphous iron hydroxysulfate Na 3 Fe 3 (SO 4) 2 (OH) 6 has been prepared for the first time from sodium insertion into the crystalline phase NaFe 3 (SO 4) 2 (OH) 6. We show that this transformation is completely reversible, leading back to the well crystallized hexagonal phase on oxidation. This material could then be proposed as positive electrode material for Na ion batteries with a reversible capacity of 120 mAh/g at 2.72 V vs Na+/Na.
sci-hub.se 参考文章(28)
Prabeer Barpanda, Gosuke Oyama, Chris D. Ling, Atsuo Yamada, Kröhnkite-Type Na2Fe(SO4)2·2H2O as a Novel 3.25 V Insertion Compound for Na-Ion Batteries Chemistry of Materials. ,vol. 26, pp. 1297- 1299 ,(2014) , 10.1021/CM4033226
P Oliva, J Leonardi, JF Laurent, C Delmas, JJ Braconnier, M Figlarz, F Fievet, A De Guibert, None, Review of the structure and the electrochemistry of nickel hydroxides and oxy-hydroxides Journal of Power Sources. ,vol. 8, pp. 229- 255 ,(1982) , 10.1016/0378-7753(82)80057-8
G. Rousse, J. M. Tarascon, Sulfate-Based Polyanionic Compounds for Li-Ion Batteries: Synthesis, Crystal Chemistry, and Electrochemistry Aspects Chemistry of Materials. ,vol. 26, pp. 394- 406 ,(2014) , 10.1021/CM4022358
Sung-Wook Kim, Dong-Hwa Seo, Xiaohua Ma, Gerbrand Ceder, Kisuk Kang, Electrode Materials for Rechargeable Sodium-Ion Batteries: Potential Alternatives to Current Lithium-Ion Batteries Advanced Energy Materials. ,vol. 2, pp. 710- 721 ,(2012) , 10.1002/AENM.201200026
R VANDOORN, I FULLARTON, R DESOUZA, J KILNER, H BOUWMEESTER, A BURGGRAAF, Surface oxygen exchange of La0.3Sr0.7CoO3-d Solid State Ionics. ,vol. 96, pp. 1- 7 ,(1997) , 10.1016/S0167-2738(97)00011-8
Rajesh Tripathi, T. N. Ramesh, Brian L. Ellis, Linda F. Nazar, Scalable Synthesis of Tavorite LiFeSO4F and NaFeSO4F Cathode Materials Angewandte Chemie. ,vol. 49, pp. 8738- 8742 ,(2010) , 10.1002/ANIE.201003743
A Zuev, L Singheiser, K Hilpert, Defect structure and isothermal expansion of A-site and B-site substituted lanthanum chromites Solid State Ionics. ,vol. 147, pp. 1- 11 ,(2002) , 10.1016/S0167-2738(02)00010-3
Hyungsub Kim, Inchul Park, Dong-Hwa Seo, Seongsu Lee, Sung-Wook Kim, Woo Jun Kwon, Young-Uk Park, Chul Sung Kim, Seokwoo Jeon, Kisuk Kang, New iron-based mixed-polyanion cathodes for lithium and sodium rechargeable batteries: combined first principles calculations and experimental study. Journal of the American Chemical Society. ,vol. 134, pp. 10369- 10372 ,(2012) , 10.1021/JA3038646
Brent C. Melot, David O. Scanlon, Marine Reynaud, Gwenaëlle Rousse, Jean-Noël Chotard, Marc Henry, Jean-Marie Tarascon, Chemical and structural indicators for large redox potentials in Fe-based positive electrode materials. ACS Applied Materials & Interfaces. ,vol. 6, pp. 10832- 10839 ,(2014) , 10.1021/AM405579H
Hyungsub Kim, Inchul Park, Seongsu Lee, Hyunchul Kim, Kyu-Young Park, Young-Uk Park, Haegyeom Kim, Jongsoon Kim, Hee-Dae Lim, Won-Sub Yoon, Kisuk Kang, Understanding the Electrochemical Mechanism of the New Iron-Based Mixed-Phosphate Na4Fe3(PO4)2(P2O7) in a Na Rechargeable Battery Chemistry of Materials. ,vol. 25, pp. 3614- 3622 ,(2013) , 10.1021/CM4013816