The Effect of Bromination on the Melting Point and Heat of Fusion of Polyethylene Single Crystals

作者: Ian R. Harrison , Eric Baer

DOI: 10.1007/978-1-4615-8621-0_3

关键词:

摘要: The demonstration that the chain axis of a polymer is approximately perpendicular(1) to lamella face initiated controversy on nature fold. Use primarily physical methods has not been successful in determining degree surface roughness, which still question(2). Chemical attack fold particularly PE mainly resulted degradation polymer(3). However chemical modification followed by application reported(4). It felt this kind work will prove useful only as an extension analytical techniques but also means modifying those properties are sensitive surface. In addition selective could produce novel block copolymers may themselves be precursors other copolymers, gels or rubbers.

参考文章(21)
R. P. Palmer, A. J. Cobbold, The texture of melt crystallised polythene as revealed by selective oxidation Macromolecular Chemistry and Physics. ,vol. 74, pp. 174- 189 ,(1964) , 10.1002/MACP.1964.020740114
M. Dole, B. Wunderlich, Melting points and heats of fusion of polymers and copolymers Macromolecular Chemistry and Physics. ,vol. 34, pp. 29- 49 ,(1959) , 10.1002/MACP.1959.020340102
D.C. Bassett, On the chemistry of polymer chain folds Polymer. ,vol. 5, pp. 457- 462 ,(1964) , 10.1016/0032-3861(64)90193-4
Keiichi Nambu, Studies on chlorinated polyethylenes. I. Infrared spectra of chlorinated polyethylenes Journal of Applied Polymer Science. ,vol. 4, pp. 69- 73 ,(1960) , 10.1002/APP.1960.070041010
Fumiyuki Hamada, Bernhard Wunderlich, Takuji Sumida, Seiichi Hayashi, Akio Nakajima, Density and heat of fusion of folded chain polyethylene crystals The Journal of Physical Chemistry. ,vol. 72, pp. 178- 185 ,(1968) , 10.1021/J100847A034
Ian R Harrison, Eric Baer, Reactions at the fold surface of polyvinylidene chloride crystals Journal of Colloid and Interface Science. ,vol. 31, pp. 176- 187 ,(1969) , 10.1016/0021-9797(69)90324-5
H.E. Bair, R. Salovey, T.W. Huseby, Melting and annealing of polyethylene single crystals Polymer. ,vol. 8, pp. 9- 20 ,(1967) , 10.1016/0032-3861(67)90003-1
R. Salovey, D. C. Bassett, Irradiation of Annealed Polyethylene Crystals Journal of Applied Physics. ,vol. 35, pp. 3216- 3221 ,(1964) , 10.1063/1.1713201