Experimental and modeling study of the oxidation of toluene

作者: R. Bounaceur , I. Da Costa , R. Fournet , F. Billaud , F. Battin-Leclerc

DOI: 10.1002/KIN.20047

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摘要: This paper describes an experimental and modeling study of the oxidation of toluene. The low‐temperature oxidation was studied in a continuous flow stirred tank reactor with carbon‐containing products analyzed by gas chromatography under the following experimental conditions: temperature from 873 to 923 K, 1 bar, fuel equivalence ratios from 0.45 to 0.91, concentrations of toluene from 1.4 to 1.7%, and residence times ranging from 2 to 13 s corresponding to toluene conversion from 5 to 85%. The ignition delays of toluene–oxygen …

参考文章(43)
V. Subba Rao, Gordon B. Skinner, Formation of hydrogen and deuterium atoms in the pyrolysis of toluene-d8 and toluene-.alpha.,.alpha.,.alpha.-d3 behind shock waves The Journal of Physical Chemistry. ,vol. 93, pp. 1864- 1869 ,(1989) , 10.1021/J100342A033
P. Dagaut, G. Pengloan, A. Ristori, Oxidation, ignition and combustion of toluene: Experimental and detailed chemical kinetic modeling Physical Chemistry Chemical Physics. ,vol. 4, pp. 1846- 1854 ,(2002) , 10.1039/B110282F
K. M. Pamidimukkala, R. D. Kern, M. R. Patel, H. C. Wei, J. H. Kiefer, High-temperature pyrolysis of toluene The Journal of Physical Chemistry. ,vol. 91, pp. 2148- 2154 ,(1987) , 10.1021/J100292A034
T. Ingham, R.W. Walker, R.E. Woolford, Kinetic parameters for the initiation reaction RH+O2→R+HO2 Symposium (International) on Combustion. ,vol. 25, pp. 767- 774 ,(1994) , 10.1016/S0082-0784(06)80709-5
R. Fournet, J. C. Bauge, F. Battin-Leclerc, Experimental and modeling of oxidation of acetylene, propyne, allene and 1,3-butadiene International Journal of Chemical Kinetics. ,vol. 31, pp. 361- 379 ,(1999) , 10.1002/(SICI)1097-4601(1999)31:5<361::AID-KIN6>3.0.CO;2-K
H Hippler, C Reihs, J Troe, None, Shock tube UV absorption study of the oxidation of benzyl radicals Symposium (International) on Combustion. ,vol. 23, pp. 37- 43 ,(1991) , 10.1016/S0082-0784(06)80239-0
E. Heckmann, H. Hippler, J. Troe, High-temperature reactions and thermodynamic properties of phenyl radicals Symposium (International) on Combustion. ,vol. 26, pp. 543- 550 ,(1996) , 10.1016/S0082-0784(96)80258-X
Stephen D. Klotz, Kenneth Brezinsky, Irvin Glassman, Modeling the combustion of toluene-butane blends Symposium (International) on Combustion. ,vol. 27, pp. 337- 344 ,(1998) , 10.1016/S0082-0784(98)80421-9
M.B. Colket, D.J. Seery, Reaction mechanisms for toluene pyrolysis Symposium (International) on Combustion. ,vol. 25, pp. 883- 891 ,(1994) , 10.1016/S0082-0784(06)80723-X
Yewen Tan, Peter Frank, A detailed comprehensive kinetic model for benene oxidation using the recent kinetic results Symposium (International) on Combustion. ,vol. 26, pp. 677- 684 ,(1996) , 10.1016/S0082-0784(96)80275-X