The Emerging Mechanistic Picture

作者: R. J. Fleming

DOI: 10.1007/978-1-4419-1591-7_10

关键词:

摘要: Electron energy band structure in polymers, particularly polyethylene, and electron injection, transport trapping are briefly reviewed. The interface model of polymer nanocomposites is then described, the Tanaka et al. Lewis formulations outlined context a mechanistic understanding. Detailed discussion several recent papers, presenting DC conductivity space charge data for seven different polymer/nanoparticle combinations, follows. main findings each combination summarized. It concluded that accumulation discussed do not specifically endorse nanodielectrics. Rather presented can be interpreted satisfactorily, though detail, using established models percolation theory. Finally, broad tentative guidelines tailoring properties presented.

参考文章(73)
Hossein Borsi, Ernst Gockenbach, Jiaosuo Zhang, Xiang Zhang, Ed Cherney, Stéphane Holé, Louise Audrieth, Robert Fleming, 7 Recent Developments in the Pressure Wave Propagation Method ,(2009)
T. D. Yares'ko, V. A. Baryshev, Specific bulk electrical resistance of two-component mixtures of dispersed materials Pharmaceutical Chemistry Journal. ,vol. 14, pp. 341- 343 ,(1980) , 10.1007/BF00777407
P. Fischer, P. Röhl, Transient currents in oxidized low-density polyethylene Steinkopff. pp. 149- 153 ,(1977) , 10.1007/BFB0117106
Christopher M. A. Brett, Ana Maria Oliveira Brett, Electrochemistry: Principles, Methods, and Applications ,(1993)
J. Mort, G. Pfister, Electronic properties of polymers ,(1982)
J. C. Fothergill, L. A. Dissado, Electrical degradation and breakdown in polymers ,(1992)
Catalin Picu, Pawel Keblinski, Modeling of Nanocomposites Wiley‐VCH Verlag GmbH & Co. KGaA. pp. 215- 222 ,(2004) , 10.1002/3527602127.CH4
HJ Wintle, Conduction Processes in Polymers ASTM International. ,(1983) , 10.1520/STP37838S
David Cubero, Nicholas Quirke, David F. Coker, Electronic states for excess electrons in polyethylene compared to long-chain alkanes Chemical Physics Letters. ,vol. 370, pp. 21- 25 ,(2003) , 10.1016/S0009-2614(03)00046-0
Roald Hoffmann, Christoph Janiak, Christian Kollmar, A Chemical Approach to the Orbitals of Organic Polymers Macromolecules. ,vol. 24, pp. 3725- 3746 ,(1991) , 10.1021/MA00013A001