Perspectives in Modern Voltammetry: Basic Concepts and Mechanistic Analysis

摘要: Publisher Summary Voltammetric techniques have become popular since the 1940s when instrumentation required to conduct such experiments became readily available. considered in this chapter involve monitoring current a time-dependent potential is applied an electrochemical cell. The measured results from frequently complex combinations of heterogeneous (in which electron transferred at solutionelectrode interface) and homogeneous processes (which occur solution phase). early studies invariably used linear sweep DC technique. In last 50 years, wide range interest emerged. This describes voltammetric based on use inherently simple waveforms (linear, cyclic or staircase). description begins level that presupposes only limited prior knowledge suitable for those unfamiliar with application elucidation electrode reaction mechanisms. also focuses typical phase mechanisms encountered organic organometallic electrochemistry.