Photolysis of formaldehyde as a hydrogen atom source in the lower atmosphere.

作者: J. G. Calvert , J. A. Kerr , K. L. Demerjian , R. D. McQuigg

DOI: 10.1126/SCIENCE.175.4023.751

关键词:

摘要: The rates of formaldehyde photodecomposition into hydrogen and formyl radicals carbon monoxide molecules in sunlightirradiated atmospheres have been estimated from extinction data photochemical results. These should prove useful the development models for chemical changes that take place polluted atmosphere.

参考文章(4)
Robert D. McQuigg, Jack G. Calvert, Photodecomposition of CH2O, CD2O, CHDO, and CH2O-CD2O mixtures at xenon flash lamp intensities Journal of the American Chemical Society. ,vol. 91, pp. 1590- 1599 ,(1969) , 10.1021/JA01035A002
K. Westberg, N. Cohen, K. W. Wilson, Carbon monoxide: its role in photochemical smog formation. Science. ,vol. 171, pp. 1013- 1015 ,(1971) , 10.1126/SCIENCE.171.3975.1013
Benjamin A. DeGraff, Jack G. Calvert, A study of the primary processes in CH2O and CD2O photolyses Journal of the American Chemical Society. ,vol. 89, pp. 2247- 2253 ,(1967) , 10.1021/JA00986A002