Internal Rotation II The Energy Difference between the Rotational Isomers of 1,2‐Dichloroethane

作者: H. J. Bernstein

DOI: 10.1063/1.1747235

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摘要: From the variation of intensities infra‐red bands with temperature value ΔH0 for reaction C2h dichloroethane →C2 is found to be 1250±50 cals. per mole. The probable energy difference between isomers 1100±50 cal. A tentative assignment all fundamentals has been made.Peak and integrated yield same results within limits experimental error. ratio number C2 molecules at room 0.29.

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