The development of a simple general procedure for synthesis of pure enantiomers via chiral organoboranes
作者： Herbert C. Brown , Bakthan Singaram
DOI: 10.1021/AR00152A001
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sci-hub.se 参考文章(35)
Herbert C. Brown, Prabhakar K. Jadhav, Arun K. Mandal, Asymmetric syntheses via chiral organoborane reagents Tetrahedron. ,vol. 37, pp. 3547- 3587 ,(1981) , 10.1016/S0040-4020(01)98886-6
Bernhard Koppenhoefer, Roland Weber, Volker Schurig, A Useful Route to (R)-Alkyloxiranes of Defined Enantiomeric Purity from (S)-Amino Acids Synthesis. ,vol. 1982, pp. 316- 318 ,(1982) , 10.1055/S-1982-29796
Herbert C. Brown, Raman K. Bakshi, Bakthan. Singaram, Chiral synthesis via organoboranes. 12. Conversion of boronic esters of essentially 100% optical purity into monoalkylthexylboranes providing convenient synthetic routes to trans-olefins, cis-olefins, alkynes, and ketones of very high enantiomeric purities Journal of the American Chemical Society. ,vol. 110, pp. 1529- 1534 ,(1988) , 10.1021/JA00213A028
Kenji Mori, Hindenori Watanabe, Synthesis of the propionates of (2r, 8r)- and (2s, 8r)-8-methyl-2-decanol, the pheromone of the western corn rootworm, employing chiral compounds of microbial origin as starting materials Tetrahedron. ,vol. 40, pp. 299- 303 ,(1984) , 10.1016/S0040-4020(01)91175-5
Herbert C. Brown, J. V. N. Vara. Prasad, Chiral synthesis via organoboranes. 6. Hydroboration. 74. Asymmetric hydroboration of representative heterocyclic olefins with diisopinocampheylborane. Synthesis of heterocyclic boronates and heterocyclic alcohols of very high enantiomeric purity Journal of the American Chemical Society. ,vol. 108, pp. 2049- 2054 ,(1986) , 10.1021/JA00268A053
Herbert C. Brown, Toshiro Imai, Manoj C. Desai, Bakthan Singaram, Chiral synthesis via organoboranes. 3. Conversion of boronic esters of essentially 100% optical purity to aldehydes, acids, and homologated alcohols of very high enantiomeric purities Journal of the American Chemical Society. ,vol. 107, pp. 4980- 4983 ,(1985) , 10.1021/JA00303A026
Charles A. Brown, Manoj C. Desai, Prabhakav K. Jadhav, Enantioselective synthesis of disubstituted alkynes via organoboranes Journal of Organic Chemistry. ,vol. 51, pp. 162- 167 ,(1986) , 10.1021/JO00352A007
Herbert C. Brown, Bakthan Singaram, Hydroboration. 68. Chiral synthesis via organoboranes. 1. A simple procedure to achieve products of essentially 100% optical purity in hydroboration of alkenes with monoisopinocampheylborane. Synthesis of boronic esters and derived products of very high enantiomeric purities Journal of the American Chemical Society. ,vol. 106, pp. 1797- 1800 ,(1984) , 10.1021/JA00318A040
Herbert C. Brown, J. V. N. Vara Prasad, Ashok K. Gupta, Raman K. Bakshi, Hydroboration. 80. Preparation of trans-2-phenylcyclopentyl- and trans-2-phenylcyclohexylboronates of very high enantiomeric purities Journal of Organic Chemistry. ,vol. 52, pp. 310- 311 ,(1987) , 10.1021/JO00378A037
Herbert C. Brown, Ashok K. Gupta, J. V. N. Vara Prasad, Morris Srebnik, Chiral synthesis via organoboranes. 17. Preparation of .alpha.-chiral .alpha.'-alkynyl ketones of high enantiomeric excess from optically pure organyl(1-alkynyl)borinic esters Journal of Organic Chemistry. ,vol. 53, pp. 1391- 1394 ,(1988) , 10.1021/JO00242A009