XPS study of complex species intercalated in layered inorganic ion-exchangers, before and after their use as catalysts.
作者： C. Ferragina , P. Giannoccaro , A. La Ginestra , M.A. Massucci , G. Mattogno
DOI: 10.1016/0920-5861(89)85015-1
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摘要: Abstract The first results of an XPS investigation layered zirconium phosphate phases intercalated with aromatic diamines or their complexes transition metal ions are reported. technique permits the observation that N-protonation hydrated anhydrous diamine intercalation compounds occurs to a different extent. For complex containing phases, simultaneous presence protonated, unprotonated and coordinated nitrogen atoms accounts for certain degree dishomogeneity in materials, probably due slow ion diffusion between layers. spectra used as catalysts (Pd-Cu bipyridyl phosphates) account high low activity observed during catalytic reactions, also suggest probable reaction mechanism materials process.
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Maria A Massucci, Pasquale Patrono, Anthony A.G Tomlinson, Aldo La Ginestra, Carla Ferragina, Coordination of Co2+, Ni2+ and Cu2+ to 2,9 - dimethyl - 1,10 phenanthroline intercalated in α-zirconium phosphate: Evidence for dimers Materials Research Bulletin. ,vol. 22, pp. 29- 36 ,(1987) , 10.1016/0025-5408(87)90146-2
G. Mattogno, C. Ferragina, M.A. Massucci, P. Patrono, A. La Ginestra, X-ray photoelectron spectroscopic evidence of interlayer complex formation between Co(II) and N-heterocycles in α-Zr(hpo4)2 · H2O Journal of Electron Spectroscopy and Related Phenomena. ,vol. 46, pp. 285- 295 ,(1988) , 10.1016/0368-2048(88)85026-6
Potenzo Giannoccaro, Palladium-catalysed N,N′-disubstituted urea synthesis by oxidative carbonylation of amines under CO and O2 at atmospheric pressure Journal of Organometallic Chemistry. ,vol. 336, pp. 271- 278 ,(1987) , 10.1016/0022-328X(87)87174-7
Sven Larsson, Shake-up and multiplet structure of ESCA satellites of Cu compounds Chemical Physics Letters. ,vol. 40, pp. 362- 366 ,(1976) , 10.1016/0009-2614(76)85097-X
Carla Ferragina, Maria Massucci, Aldo La Ginestra, Pasquale Patrono, Anthony A. G. Tomlinson, Diffusion of large amine ligands into layered α-Zr(HPO4)2·H2O. Access to a solid-state co-ordination chemistry Journal of The Chemical Society, Chemical Communications. pp. 1024- 1025 ,(1984) , 10.1039/C39840001024
Carla Ferragina, Aldo La Ginestra, Maria Antonietta Massucci, Pasquale Patrono, Anthony A. G. Tomlinson, Intercalation of 2,2'-bipyridyl into .alpha.-zirconium phosphate and in situ formation of cobalt(2+), nickel(2+), and copper(2+)/2,2'-bipyridyl complex pillars The Journal of Physical Chemistry. ,vol. 89, pp. 4762- 4769 ,(1985) , 10.1021/J100268A022
Carla Ferragina, Maria A. Massucci, Pasquale Patrono, Aldo La Ginestra, Anthony A. G. Tomlinson, Pillaring of layers in α-zirconium phosphate by 1,10-phenanthroline and bis(1,10-phenanthroline)copper(II): formation of complex pillars in situ J. Chem. Soc., Dalton Trans.. pp. 265- 271 ,(1986) , 10.1039/DT9860000265
Carla Ferragina, Maria A. Massucci, Pasquale Patrono, Aldo La Ginestra, Anthony A. G. Tomlinson, Pillar chemistry. Part 4. Palladium(II)–2,2′-bipyridyl, –1,10-phenanthroline, and –2,9-dimethyl-1,10-phenanthroline complex pillars in α-zirconium phosphate J. Chem. Soc., Dalton Trans.. pp. 851- 857 ,(1988) , 10.1039/DT9880000851
K.S. Kim, Charge transfer transition accompanying x-ray photoionization in transition-metal compounds Journal of Electron Spectroscopy and Related Phenomena. ,vol. 3, pp. 217- 226 ,(1974) , 10.1016/0368-2048(74)80012-5