Structural effects in electrocatalysis

作者: C. Lamy , J.M. Leger , J. Clavilier , R. Parsons

DOI: 10.1016/S0022-0728(83)80191-0

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摘要: Abstract The electrocatalytic oxidation of CO, HCOOH and CH3OH is compared on Pt(100), Pt(110) Pt(111) single crystals. similarity behaviour CO the three crystal planes leads to conclusion that both compounds involves CO-like intermediates. On other hand, behaves quite differently, particularly Pt(100) electrodes, i.e its different adsorbed intermediates, some them being poisoning species formed in hydrogen region.

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