The photocatalytic autoxidation of sulfur oxoanions by water-soluble porphyrin complexes
作者： Shen-Ming Chen , None
DOI: 10.1016/S1381-1169(98)00148-4
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摘要: Abstract The photocatalytic autoxidation of S 4 O 6 2− and 2 3 by water-soluble porphyrin complexes Fe(2-TMPyP), Mn(4-TMPyP), Co(2-TMPyP) were compared under illumination with a 419 nm visible light in oxygen-saturated aqueous solutions at room temperature. process involves as an intermediate product SO is the final oxidation product. trend activity for Co(2-TMPyP)>Mn(4-TMPyP)>Fe(2-TMPyP). For oxidation, Co(2-TMPyP)>Fe(2-TMPyP)>Mn(4-TMPyP).
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